NR 465.25(2)(g)2.2. The calculations used to determine the organic HAP emission rate for each compliance period in which a deviation occurred. You shall provide the calculation of the total mass of organic HAP emissions for the coatings, thinners and cleaning materials used during the compliance period using Equations 1, 1A to 1C and 2 of s. NR 465.27 (2) and, if applicable, the calculation used to determine the mass of organic HAP in waste materials according to s. NR 465.27 (2) (e) 2.; the calculation of the total volume of coating solids used during the compliance period using Equation 2 of s. NR 465.27 (2); the calculation of the mass of organic HAP emission reduction during the compliance period by emission capture systems and add-on control devices, using Equations 1, 1A to 1C, 2, 3 and 3A to 3C of s. NR 465.28 (2); and the calculation of the organic HAP emission rate, using Equation 4 of s. NR 465.28 (2). You do not need to submit the background data supporting these calculations, for example, information provided by materials suppliers or manufacturers or test reports. NR 465.25(2)(g)6.6. The date and time that each CPMS was inoperative, except for zero (low-level) and high-level checks. NR 465.25(2)(g)8.8. The date and time period of each deviation from an operating limit in Table 1 of this subchapter, the date and time period of any bypass of the add-on control device, and whether each deviation occurred during a period of startup, shutdown or malfunction or during another period. NR 465.25(2)(g)9.9. A summary of the total duration of each deviation from an operating limit in Table 1 of this subchapter and bypass of the add-on control device during the semiannual reporting period and the total duration as a percent of the total source operating time during that semiannual reporting period. NR 465.25(2)(g)10.10. A breakdown of the total duration of the deviations from the operating limits in Table 1 of this subchapter and bypasses of the add-on control device during the semiannual reporting period into those that were due to startup, shutdown, control equipment problems, process problems, other known causes and other unknown causes. NR 465.25(2)(g)11.11. A summary of the total duration of CPMS downtime during the semiannual reporting period and the total duration of CPMS downtime as a percent of the total source operating time during that semiannual reporting period. NR 465.25(2)(g)12.12. A description of any changes in the CPMS, coating operation, emission capture system or add-on control device since the last semiannual reporting period. NR 465.25(2)(g)13.13. For each deviation from the work practice standards, a description of the deviation, the date and time period of the deviation and the actions you took to correct the deviation. NR 465.25(2)(h)(h) If you use the emission rate with add-on controls option, you shall submit reports of performance test results for emission capture systems and add-on control devices no later than 60 days after completing the tests as specified in s. NR 460.09 (4) (b). NR 465.25(2)(j)(j) If you use the emission rate with add-on controls option and you have a startup, shutdown or malfunction during the semiannual reporting period, you shall submit the following reports as applicable: NR 465.25(2)(j)1.1. If your actions were consistent with your startup, shutdown and malfunction plan (SSMP), you shall include the information specified in s. NR 460.09 (4) (e) in the semiannual compliance report required by par. (a). NR 465.25(2)(j)2.2. If your actions were not consistent with your SSMP, you shall submit an immediate startup, shutdown and malfunction report as follows: NR 465.25(2)(j)2.a.a. You shall describe the actions taken during the event in a report delivered by facsimile, telephone or other means to the department within 2 working days after starting actions that are inconsistent with the plan. NR 465.25(2)(j)2.b.b. You shall submit a letter to the department within 7 working days after the end of the event, unless you have made alternative arrangements with the department as specified in s. NR 460.09 (4) (e) 3. The letter shall contain the information specified in s. NR 460.09 (4) (e) 2. NR 465.25(3)(3) What records must I keep?. You shall collect and keep records of the data and information specified in this subsection. Failure to collect and keep these records is a deviation from the applicable standard. The data and information are as follows: NR 465.25(3)(a)(a) Each notification and report that you submitted to comply with this subchapter and the documentation supporting each notification and report. NR 465.25(3)(b)(b) Information provided by materials suppliers or manufacturers such as manufacturer’s formulation data or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and cleaning material and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP, density or volume fraction of coating solids, a copy of the complete test report. If you use information provided to you by the manufacturer or supplier of the material that was based on testing, the summary sheet of results provided to you by the manufacturer or supplier. You are not required to obtain the test report or other supporting documentation from the manufacturer or supplier. NR 465.25(3)(c)(c) For each compliance period, the time periods (beginning and ending dates and times) and the coating operations at which each compliance option was used and all determinations of kg organic HAP per liter of coating solids for the compliance option or options you used, as follows: NR 465.25(3)(c)2.2. For the emission rate without add-on controls option, the calculation of the total mass of organic HAP emissions for the coatings, thinners, and cleaning materials used each month, using Equations 1 and 1A to 1C of s. NR 465.27 (2) and, if applicable, the calculations used to determine the mass of organic HAP in waste materials according to s. NR 465.27 (2) (e) 2.; the calculation of the total volume of coating solids used each month, using Equation 2 of s. NR 465.27 (2); and the calculation of the organic HAP emission rate, using Equation 3 of s. NR 465.27 (2). NR 465.25(3)(c)3.3. For the emission rate with add-on controls option, the calculation of the total mass of organic HAP emissions for the coatings, thinners and cleaning materials used each month, using Equations 1 and 1A to 1C of s. NR 465.27 (2) and, if applicable, the calculation used to determine mass of organic HAP in waste materials according to s. NR 465.27 (2) (e) 2.; the calculation of the total volume of coating solids used each month, using Equation 2 of s. NR 465.27 (2); the calculation of the mass of organic HAP emission reduction by emission capture systems and add-on control devices, using Equations 1, 1A to 1C, 2, 3 and 3A to 3C of s. NR 465.28 (2), as applicable; and the calculation of the organic HAP emission rate, using Equation 4 of s. NR 465.28 (2). NR 465.25(3)(d)(d) The name and volume of each coating, thinner and cleaning material used during each compliance period. NR 465.25(3)(e)(e) The mass fraction of organic HAP for each coating, thinner and cleaning material used during each compliance period. NR 465.25(3)(f)(f) The volume fraction of coating solids for each coating used during each compliance period except for zero-HAP coatings for which volume solids determination is not required as allowed in s. NR 465.26 (2) (a). NR 465.25(3)(g)(g) The density for each coating used during each compliance period except for zero-HAP coatings for which volume solids determination is not required as allowed in s. NR 465.26 (2) (a) and, if you use either the emission rate without add-on controls or the emission rate with add-on controls compliance option, the density for each thinner and cleaning material used during each compliance period. NR 465.25(3)(h)(h) If you use an allowance in Equation 1 of s. NR 465.27 (2) for organic HAP contained in waste materials sent to or designated for shipment to a treatment, storage and disposal facility (TSDF) according to s. NR 465.27 (2) (e) 2., all of the following information: NR 465.25(3)(h)1.1. The name and address of each TSDF to which you sent waste materials for which you use an allowance in Equation 1 of s. NR 465.27 (2), a statement of which subparts under 40 CFR parts 262, 264, 265 and 266 apply to the facility, and the date of each shipment. NR 465.25(3)(h)2.2. Identification of the coating operations producing waste materials included in each shipment and the month or months in which you used the allowance for these materials in Equation 1 of s. NR 465.27 (2). NR 465.25(3)(h)3.3. The methodology used in accordance with s. NR 465.27 (2) (e) 2. to determine the total amount of waste materials sent to, or the amount collected, stored and designated for transport to, a TSDF each month, and the methodology to determine the mass of organic HAP contained in these waste materials. This shall include the sources for all data used in the determination, methods used to generate the data, frequency of testing or monitoring, and supporting calculations and documentation, including the waste manifest for each shipment. NR 465.25(3)(k)(k) If you use the emission rate with add-on controls option, all of the following: NR 465.25(3)(k)1.1. For each deviation, whether the deviation occurred during a period of startup, shutdown or malfunction. NR 465.25(3)(k)3.3. The records required to show continuous compliance with each operating limit specified in Table 1 of this subchapter that applies to you. NR 465.25(3)(k)4.4. For each capture system that is a PTE, the data and documentation you used to support a determination that the capture system meets the criteria in Method 204 in 40 CFR part 51, Appendix M, incorporated by reference in s. NR 484.04 (9), for a PTE and has a capture efficiency of 100%, as specified in s. NR 465.28 (6) (a). NR 465.25(3)(k)5.5. For each capture system that is not a PTE, the data and documentation you used to determine capture efficiency according to the requirements specified in s. NR 465.28 (5) and (6) (b), including the following as applicable: NR 465.25(3)(k)5.a.a. For a liquid-to-uncaptured-gas protocol using a temporary total enclosure or building enclosure, the mass of total volatile hydrocarbon (TVH) as measured by Method 204A or 204F in 40 CFR part 51, Appendix M, incorporated by reference in s. NR 484.04 (9), for each material used in the coating operation, and the total TVH for all materials used during each capture efficiency test run, including a copy of the test report. Also the mass of TVH emissions not captured by the capture system that exited the temporary total enclosure or building enclosure during each capture efficiency test run, as measured by Method 204D or 204E in 40 CFR part 51, Appendix M, incorporated by reference in s. NR 484.04 (9), including a copy of the test report, and documentation that the enclosure used for the capture efficiency test met the criteria in Method 204 in 40 CFR part 51, Appendix M, for either a temporary total enclosure or a building enclosure. NR 465.25(3)(k)5.b.b. For a gas-to-gas protocol using a temporary total enclosure or a building enclosure, the mass of TVH emissions captured by the emission capture system as measured by Method 204B or 204C in 40 CFR part 51, Appendix M, incorporated by reference in s. NR 484.04 (9), at the inlet to the add-on control device, including a copy of the test report. Also, the mass of TVH emissions not captured by the capture system that exited the temporary total enclosure or building enclosure during each capture efficiency test run, as measured by Method 204D or E in 40 CFR part 51, Appendix M, including a copy of the test report, and documentation that the enclosure used for the capture efficiency test met the criteria in Method 204 in 40 CFR part 51, Appendix M, for either a temporary total enclosure or a building enclosure. NR 465.25(3)(k)5.c.c. For an alternative protocol, documentation of a capture efficiency determination using an alternative method or protocol as specified in s. NR 465.28 (6) (b) 3., if applicable. NR 465.25(3)(k)6.6. For each add-on control device organic HAP destruction or removal efficiency determination as specified in s. NR 465.28 (7), all of the following: NR 465.25(3)(k)6.b.b. The coating operation conditions during the add-on control device performance test showing that the performance test was conducted under representative operating conditions. NR 465.25(3)(k)8.8. The data and calculations you used to establish the emission capture and add-on control device operating limits as specified in s. NR 465.28 (8), and to document compliance with the operating limits as specified in Table 1 of this subchapter. NR 465.25(4)(4) In what form and for how long must I keep my records?. NR 465.25(4)(a)(a) Your records shall be in a form suitable and readily available for expeditious review, according to s. NR 460.09 (2) (a). Where appropriate, the records may be maintained as electronic spreadsheets or as a database. NR 465.25(4)(b)(b) As specified in s. NR 460.09 (2) (a), you shall keep each record for 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. NR 465.25(4)(c)(c) You shall keep each record on site for at least 2 years after the date of each occurrence, measurement, maintenance, corrective action, report or record, according to s. NR 460.09 (2) (a). You may keep the records off site for the remaining 3 years. NR 465.25 HistoryHistory: CR 03-037: cr. Register March 2004 No. 579, eff. 4-1-04. NR 465.26NR 465.26 Compliance requirements for the compliant material option. NR 465.26(1)(1) By what date must I conduct the initial compliance demonstration?. You shall complete the initial compliance demonstration for the initial compliance period according to the requirements in sub. (2). The initial compliance period begins on the applicable compliance date specified in s. NR 465.21 (4) and ends on the last day of the first full month after the compliance date. If the compliance date occurs on any day other than the first day of a month, then the initial compliance period extends through the end of that month plus the next month. The initial compliance demonstration includes the determination according to sub. (2) and supporting documentation showing that, during the initial compliance period, you used no coating with an organic HAP content that exceeded the applicable emission limit in s. NR 465.23 (1), and that you used no thinners or cleaning materials that contained organic HAP. NR 465.26(2)(2) How do I demonstrate initial compliance with the emission limitations?. You may use the compliant material option for any individual coating operation, for any group of coating operations in the affected source, or for all the coating operations in the affected source. You shall use either the emission rate without add-on controls option or the emission rate with add-on controls option for any coating operation in the affected source for which you do not use this option. To demonstrate initial compliance using the compliant material option, the coating operation or group of coating operations may not use any coating with an organic HAP content that exceeds the applicable emission limit in s. NR 465.23 (1) and may not use any thinner or cleaning material that contains organic HAP, as determined according to this section during the initial compliance period. Any coating operation or operations for which you use the compliant material option is not required to meet the operating limits or work practice standards required in s. NR 465.23 (3) and (4), respectively. To demonstrate initial compliance with the emission limitations using the compliant material option, you shall meet all the requirements of this subsection for the coating operation or operations using this option. You shall use the procedures in this subsection on each coating, thinner and cleaning material in the condition it is in when it is received from its manufacturer or supplier and prior to any alteration. You do not need to redetermine the HAP content of coatings, thinners or cleaning materials that have been reclaimed onsite and reused in the coating operation or operations for which you use the compliant material option, provided these materials, in their condition as received, were demonstrated to comply with the compliant material option. You shall comply with the following requirements and procedures except that if the mass fraction of organic HAP of a coating equals zero, determined according to par. (a), and you use the compliant material option, you are not required to comply with pars. (b) and (c) for that coating: NR 465.26(2)(a)(a) Determine the mass fraction of organic HAP for each coating, thinner and cleaning material used during the compliance period according to one of the following options: NR 465.26(2)(a)1.a.a. Count each organic HAP that is measured to be present at 0.1% by mass or more for Occupational Safety and Health Administration (OSHA) defined carcinogens as specified in 29 CFR 1910.1200 (d) (4) and at 1.0% by mass or more for other organic HAP compounds. NR 465.26 NoteNote: For example, if toluene, not an OSHA carcinogen, is measured to be 0.5% of the material by mass, you do not have to count it. Express the mass fraction of each organic HAP you count as a value truncated to 4 places after the decimal point (for example, 0.3791).
NR 465.26(2)(a)1.b.b. Calculate the total mass fraction of organic HAP in the test material by adding up the individual organic HAP mass fractions and truncating the result to 3 places after the decimal point. NR 465.26(2)(a)2.2. Use Method 24 in 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (13), for coatings to determine the mass fraction of nonaqueous volatile matter and use that value as a substitute for mass fraction of organic HAP. NR 465.26(2)(a)3.3. Use an alternative test method once the administrator has approved it. You shall follow the procedure in s. NR 460.06 (5) to submit an alternative test method for approval. NR 465.26(2)(a)4.4. Use information other than that generated by the test methods specified in subds. 1. to 3., such as manufacturer’s formulation data, if they represent each organic HAP that is present at 0.1% by mass or more for OSHA defined carcinogens as specified in 29 CFR 1910.1200 (d) (4) and at 1.0% by mass or more for other organic HAP compounds. If there is a disagreement between information relied on under this subdivision and results of a test conducted according to subds. 1. to 3., the test method results will take precedence. NR 465.26(2)(a)5.5. When test data and manufacturer’s data for solvent blends are not available, use the default values for mass fraction of organic HAP for these solvent blends listed in Table 2 or 3 of this subchapter. You shall use the values in Table 2 of this subchapter for all solvent blends that match Table 2 entries, and you may only use Table 3 of this subchapter if the solvent blends in the materials you use do not match any of the solvent blends in Table 2 of this subchapter, and you only know whether the blend is aliphatic or aromatic. However, if the results of a Method 311 test indicate higher values than those listed in Table 2 or 3 of this subchapter, the Method 311 results will take precedence. Solvent blends may be listed as single components for some materials in data provided by manufacturers or suppliers. Solvent blends may contain organic HAP which shall be counted toward the total organic HAP mass fraction of the materials. NR 465.26(2)(b)(b) Determine the volume fraction of coating solids (liters of coating solids per liter of coating) for each coating used during the compliance period according to one of the following options: NR 465.26(2)(b)1.1. Use ASTM Method D2697-86 (1998), “Standard Test Method for Volume Nonvolatile Matter in Clear or Pigmented Coatings”, or ASTM Methods D6093-97, “Standard Test Method for Percent Volume Nonvolatile Matter in Clear or Pigmented Coatings Using a Helium Gas Pycnometer”, incorporated by reference in s. NR 484.10 (39e) and (55m), respectively, to determine the volume percent of coating solids for each coating. Divide the nonvolatile volume percent obtained with the methods by 100 to calculate volume fraction of coating solids. NR 465.26(2)(b)2.2. Obtain the volume fraction of coating solids for each coating from the supplier or manufacturer of the material. NR 465.26(2)(b)3.3. If the volume fraction of coating solids cannot be determined using the options in subd. 1. or 2., use the following equation: (Equation 1)
where:
Vs is the volume fraction of coating solids, liters coating solids per liter coating
mvolatiles is the total volatile matter content of the coating, including HAP, volatile organic compounds (VOC), water and compounds excluded from the VOC definition in s. NR 400.02, determined according to Method 24 in 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (13), grams volatile matter per liter coating Davg is the average density of volatile matter in the coating, grams volatile matter per liter volatile matter, determined from test results using ASTM Method D1475-98, “Standard Test Method for Density of Liquid Coatings, Inks and Related Products”, incorporated by reference in s. NR 484.10 (22), information from the supplier or manufacturer of the material, or reference sources providing density or specific gravity data for pure materials. If there is disagreement between ASTM Method D1475-98 test results and other information sources, the test results will take precedence. NR 465.26(2)(c)(c) Determine the density of each coating used during the compliance period from test results using ASTM Method D1475-98, “Standard Test Method for Density of Liquid Coatings, Inks, and Related Products”, incorporated by reference in s. NR 484.10 (22), information from the supplier or manufacturer of the material, or reference sources providing density or specific gravity data for pure materials. If there is disagreement between ASTM Method D1475-98 test results and other information sources, the test results will take precedence. NR 465.26(2)(d)(d) Determine the organic HAP content, kg organic HAP per liter coating solids, of each coating used during the compliance period using the following equation, except that if the mass fraction of organic HAP equals zero, then the organic HAP content also equals zero: (Equation 2)
where:
Hc is the organic HAP content of the coating, kg organic HAP per liter coating solids
Dc is the density of coating, kg coating per liter coating, determined according to par.
Wc is the mass fraction of organic HAP in the coating, kg organic HAP per kg coating, determined according to par. (a)
Vs is the volume fraction of coating solids, liters coating solids per liter coating, determined according to par. (b)
NR 465.26(2)(e)(e) Ensure that the organic HAP content for each coating used during the initial compliance period is less than or equal to the applicable emission limit in s. NR 465.23 (1) and each thinner and cleaning material used during the initial compliance period does not contain any organic HAP, determined according to par. (a). You shall keep all records required by s. NR 465.25 (3) and (4). As part of the notification of compliance status required in s. NR 465.25 (1), you shall identify the coating operation or operations for which you used the compliant material option and submit a statement that the coating operation was, or operations were, in compliance with the emission limitations during the initial compliance period because you used no coatings for which the organic HAP content exceeds the applicable emission limit in s. NR 465.23 (1), and you used no thinners or cleaning materials that contain organic HAP, determined according to par. (a). NR 465.26(3)(3) How do I demonstrate continuous compliance with the emission limitations?. NR 465.26(3)(a)(a) For each compliance period, to demonstrate continuous compliance, you may not use any coating for which the organic HAP content, determined according to sub. (2) (d), exceeds the applicable emission limit in s. NR 465.23 (1), and may not use any thinner or cleaning material that contains organic HAP, determined according to sub. (2) (a). Each month following the initial compliance period described in sub. (1) is a compliance period. NR 465.26(3)(b)(b) If you choose to comply with the emission limitations by using the compliant material option, the use of any coating, thinner or cleaning material that does not meet the criteria specified in par. (a) is a deviation from the emission limitations that shall be reported as specified in s. NR 465.25 (1) (b) 6. and (2) (d).
