NR 465.26(2)(a)1.a.a. Count each organic HAP that is measured to be present at 0.1% by mass or more for Occupational Safety and Health Administration (OSHA) defined carcinogens as specified in 29 CFR 1910.1200 (d) (4) and at 1.0% by mass or more for other organic HAP compounds. NR 465.26 NoteNote: For example, if toluene, not an OSHA carcinogen, is measured to be 0.5% of the material by mass, you do not have to count it. Express the mass fraction of each organic HAP you count as a value truncated to 4 places after the decimal point (for example, 0.3791).
NR 465.26(2)(a)1.b.b. Calculate the total mass fraction of organic HAP in the test material by adding up the individual organic HAP mass fractions and truncating the result to 3 places after the decimal point. NR 465.26(2)(a)2.2. Use Method 24 in 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (13), for coatings to determine the mass fraction of nonaqueous volatile matter and use that value as a substitute for mass fraction of organic HAP. NR 465.26(2)(a)3.3. Use an alternative test method once the administrator has approved it. You shall follow the procedure in s. NR 460.06 (5) to submit an alternative test method for approval. NR 465.26(2)(a)4.4. Use information other than that generated by the test methods specified in subds. 1. to 3., such as manufacturer’s formulation data, if they represent each organic HAP that is present at 0.1% by mass or more for OSHA defined carcinogens as specified in 29 CFR 1910.1200 (d) (4) and at 1.0% by mass or more for other organic HAP compounds. If there is a disagreement between information relied on under this subdivision and results of a test conducted according to subds. 1. to 3., the test method results will take precedence. NR 465.26(2)(a)5.5. When test data and manufacturer’s data for solvent blends are not available, use the default values for mass fraction of organic HAP for these solvent blends listed in Table 2 or 3 of this subchapter. You shall use the values in Table 2 of this subchapter for all solvent blends that match Table 2 entries, and you may only use Table 3 of this subchapter if the solvent blends in the materials you use do not match any of the solvent blends in Table 2 of this subchapter, and you only know whether the blend is aliphatic or aromatic. However, if the results of a Method 311 test indicate higher values than those listed in Table 2 or 3 of this subchapter, the Method 311 results will take precedence. Solvent blends may be listed as single components for some materials in data provided by manufacturers or suppliers. Solvent blends may contain organic HAP which shall be counted toward the total organic HAP mass fraction of the materials. NR 465.26(2)(b)(b) Determine the volume fraction of coating solids (liters of coating solids per liter of coating) for each coating used during the compliance period according to one of the following options: NR 465.26(2)(b)1.1. Use ASTM Method D2697-86 (1998), “Standard Test Method for Volume Nonvolatile Matter in Clear or Pigmented Coatings”, or ASTM Methods D6093-97, “Standard Test Method for Percent Volume Nonvolatile Matter in Clear or Pigmented Coatings Using a Helium Gas Pycnometer”, incorporated by reference in s. NR 484.10 (39e) and (55m), respectively, to determine the volume percent of coating solids for each coating. Divide the nonvolatile volume percent obtained with the methods by 100 to calculate volume fraction of coating solids. NR 465.26(2)(b)2.2. Obtain the volume fraction of coating solids for each coating from the supplier or manufacturer of the material. NR 465.26(2)(b)3.3. If the volume fraction of coating solids cannot be determined using the options in subd. 1. or 2., use the following equation: (Equation 1)
where:
Vs is the volume fraction of coating solids, liters coating solids per liter coating
mvolatiles is the total volatile matter content of the coating, including HAP, volatile organic compounds (VOC), water and compounds excluded from the VOC definition in s. NR 400.02, determined according to Method 24 in 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (13), grams volatile matter per liter coating Davg is the average density of volatile matter in the coating, grams volatile matter per liter volatile matter, determined from test results using ASTM Method D1475-98, “Standard Test Method for Density of Liquid Coatings, Inks and Related Products”, incorporated by reference in s. NR 484.10 (22), information from the supplier or manufacturer of the material, or reference sources providing density or specific gravity data for pure materials. If there is disagreement between ASTM Method D1475-98 test results and other information sources, the test results will take precedence. NR 465.26(2)(c)(c) Determine the density of each coating used during the compliance period from test results using ASTM Method D1475-98, “Standard Test Method for Density of Liquid Coatings, Inks, and Related Products”, incorporated by reference in s. NR 484.10 (22), information from the supplier or manufacturer of the material, or reference sources providing density or specific gravity data for pure materials. If there is disagreement between ASTM Method D1475-98 test results and other information sources, the test results will take precedence. NR 465.26(2)(d)(d) Determine the organic HAP content, kg organic HAP per liter coating solids, of each coating used during the compliance period using the following equation, except that if the mass fraction of organic HAP equals zero, then the organic HAP content also equals zero: (Equation 2)
where:
Hc is the organic HAP content of the coating, kg organic HAP per liter coating solids
Dc is the density of coating, kg coating per liter coating, determined according to par.
Wc is the mass fraction of organic HAP in the coating, kg organic HAP per kg coating, determined according to par. (a)
Vs is the volume fraction of coating solids, liters coating solids per liter coating, determined according to par. (b)
NR 465.26(2)(e)(e) Ensure that the organic HAP content for each coating used during the initial compliance period is less than or equal to the applicable emission limit in s. NR 465.23 (1) and each thinner and cleaning material used during the initial compliance period does not contain any organic HAP, determined according to par. (a). You shall keep all records required by s. NR 465.25 (3) and (4). As part of the notification of compliance status required in s. NR 465.25 (1), you shall identify the coating operation or operations for which you used the compliant material option and submit a statement that the coating operation was, or operations were, in compliance with the emission limitations during the initial compliance period because you used no coatings for which the organic HAP content exceeds the applicable emission limit in s. NR 465.23 (1), and you used no thinners or cleaning materials that contain organic HAP, determined according to par. (a). NR 465.26(3)(3) How do I demonstrate continuous compliance with the emission limitations?. NR 465.26(3)(a)(a) For each compliance period, to demonstrate continuous compliance, you may not use any coating for which the organic HAP content, determined according to sub. (2) (d), exceeds the applicable emission limit in s. NR 465.23 (1), and may not use any thinner or cleaning material that contains organic HAP, determined according to sub. (2) (a). Each month following the initial compliance period described in sub. (1) is a compliance period. NR 465.26(3)(b)(b) If you choose to comply with the emission limitations by using the compliant material option, the use of any coating, thinner or cleaning material that does not meet the criteria specified in par. (a) is a deviation from the emission limitations that shall be reported as specified in s. NR 465.25 (1) (b) 6. and (2) (d). NR 465.26(3)(c)(c) As part of each semiannual compliance report required by s. NR 465.25 (2), you shall submit a statement that you were in compliance with the emission limitations during the reporting period because you used no thinners or cleaning materials that contained organic HAP, and you used no coatings for which the organic HAP content exceeded the applicable emission limit in s. NR 465.23 (1). NR 465.26 HistoryHistory: CR 03-037: cr. Register March 2004 No. 579, eff. 4-1-04; CR 05-040: am. (2) (a) 5. Register February 2006 No. 602, eff. 3-1-06. NR 465.27NR 465.27 Compliance requirements for the emission rate without add-on controls option. NR 465.27(1)(1) By what date must I conduct the initial compliance demonstration?. You shall complete the initial compliance demonstration for the initial compliance period according to the requirements of sub. (2). The initial compliance period begins on the applicable compliance date specified in s. NR 465.21 (4) and ends on the last day of the first full month after the compliance date. If the compliance date occurs on any day other than the first day of a month, then the initial compliance period extends through the end of that month plus the next month. The initial compliance demonstration includes the calculations according to sub. (2) and supporting documentation showing that the organic HAP emission rate for the initial compliance period was equal to or less than the applicable emission limit in s. NR 465.23 (1). NR 465.27(2)(2) How do I demonstrate initial compliance with the emission limitations?. You may use the emission rate without add-on controls option for any individual coating operation, for any group of coating operations in the affected source, or for all of the coating operations in the affected source. You shall use either the compliant material option or the emission rate with add-on controls option for any coating operation or operations in the affected source for which you do not use this option. To demonstrate initial compliance using the emission rate without add-on controls option, the coating operation or operations shall meet the applicable emission limit in s. NR 465.23 (1) but not the operating limits or work practice standards in s. NR 465.23 (3) and (4), respectively, during the initial compliance period. When calculating the organic HAP emission rate according to this subsection, you may not include any coatings, thinners or cleaning materials used on coating operations for which you use the compliant material option or the emission rate with add-on controls option. You do not need to redetermine the mass of organic HAP in coatings, thinners or cleaning materials that have been reclaimed onsite and reused in the coating operation or operations for which you use the emission rate without add-on controls option. You shall meet all of the following requirements to demonstrate initial compliance with the applicable emission limit in s. NR 465.23 (1) for the coating operation or operations: NR 465.27(2)(a)(a) Determine the mass fraction of organic HAP for each coating, thinner and cleaning material used during the compliance period according to the requirements in s. NR 465.26 (2) (a). NR 465.27(2)(b)(b) Determine the volume fraction of coating solids for each coating used during the compliance period according to the requirements in s. NR 465.26 (2) (b). NR 465.27(2)(c)(c) Determine the density of each coating, thinner and cleaning material used during the compliance period according to the requirements in s. NR 465.26 (2) (c). NR 465.27(2)(d)(d) Determine the volume (liters) of each coating, thinner and cleaning material used during the compliance period by measurement or usage records. NR 465.27(2)(e)1.1. Calculate the mass of organic HAP emissions during the compliance period using the following equations and the procedures in subd. 2. if applicable: (Equation 1)
where:
He is the total mass of organic HAP emissions during the compliance period, kg
A is the total mass of organic HAP in the coatings used during the compliance period, kg, as calculated in Equation 1A
B is the total mass of organic HAP in the thinners used during the compliance period, kg, as calculated in Equation 1B
C is the total mass of organic HAP in the cleaning materials used during the compliance period, kg, as calculated in Equation 1C
Rw is the total mass of organic HAP in waste materials sent or designated for shipment to a hazardous waste TSDF for treatment or disposal during the compliance period, kg, determined according to subd. 2. You may assign a value of zero to Rw if you do not wish to use this allowance
(Equation 1A)
where:
A is the total mass of organic HAP in the coatings used during the compliance period, kg
Volc,i is the total volume of coating, i, used during the compliance period, liters
Dc,i is the density of coating, i, kg coating per liter coating
Wc,i is the mass fraction of organic HAP in coating, i, kg organic HAP per kg coating
m is the number of different coatings used during the compliance period
(Equation 1B)
where:
B is the total mass or organic HAP in the thinners used during the compliance period, kg
Volt,j is the total volume of thinner, j, used during the compliance period, liters
Dt,j is the density of thinner, j, kg thinner per liter thinner
Wt,j is the mass fraction of organic HAP in thinner, j, kg organic HAP per kg thinner
n is the number of different thinners used during the compliance period
(Equation 1C)
where:
C is the total mass of organic HAP in the cleaning materials used during the compliance period, kg
Vols,k is the total volume of cleaning material, k, used during the compliance period, liters
Ds,k is the density of cleaning material, k, kg cleaning material per liter cleaning material
Ws,k is the mass fraction of organic HAP in cleaning material, k, kg organic HAP per kg material
p is the number of different cleaning materials used during the compliance period
NR 465.27(2)(e)2.2. If you choose to account for the mass of organic HAP contained in waste materials sent or designated for shipment to a hazardous waste TSDF in the calculation of the mass of organic HAP emissions using Equation 1, you shall determine it according to the following procedures: NR 465.27(2)(e)2.a.a. You may include in the determination of organic HAP in waste materials only the waste materials that are generated by coating operations for which you use Equation 1 in subd. 1. and that will be treated or disposed of by a facility that is regulated as a TSDF under 40 CFR part 262, 264, 265, or 266. The TSDF may be either off-site or on-site. You may not include in the determination the organic HAP contained in wastewater. NR 465.27(2)(e)2.b.b. Determine either the amount of waste materials sent to a TSDF during the compliance period or the amount collected and stored during the compliance period and designated for future transport to a TSDF. You may not include in your determination any waste materials sent to a TSDF during a compliance period if you have already included them in the amount collected and stored during that compliance period or a previous compliance period. NR 465.27(2)(e)2.e.e. To the extent that waste manifests include this information, they may be used as part of the documentation of the amount of waste materials and mass of organic HAP contained in them. NR 465.27(2)(f)(f) Determine the total volume of coating solids used, liters, which is the combined volume of coating solids for all of the coatings used during the compliance period, using the following equation: (Equation 2)
where:
Vst is the total volume of coating solids used during the compliance period, liters
Volc,i is the total volume of coating, i, used during the compliance period, liters
Vs,i is the volume fraction of coating solids for coating, i, liters solids per liter coating, determined according to s. NR 465.26 (2) (b) m is the number of coatings used during the compliance period
NR 465.27(2)(g)(g) Calculate the organic HAP emission rate, kg organic HAP per liter coating solids used, using the following equation:
