NR 440.19(7)(b)5.a.a. The sampling site and location shall be the same as for the SO2 sample. Each run shall consist of 4 grab samples, with each sample taken at about 15-minute intervals. NR 440.19(7)(b)5.b.b. For each NOx sample, the emission rate correction factor, grab sampling and analysis procedure of Method 3B shall be used to determine the O2 concentration (%O2). The sample shall be taken simultaneously with, and at the same point as, the NOx sample. NR 440.19(7)(b)5.c.c. The NOx emission rate shall be computed for each pair of NOx and O2 samples. The NOx emission rate (E) for each run shall be the arithmetic mean of the results of the 4 pairs of samples. NR 440.19(7)(c)(c) When combinations of fossil fuels or fossil fuel and wood residue are fired, the owner or operator, in order to compute the prorated standard as shown in subs. (4) (b) and (5) (b), shall determine the percentage (w, x, y, or z) of the total heat input derived from each type of fuel as follows: NR 440.19(7)(c)1.1. The heat input rate of each fuel shall be determined by multiplying the gross calorific value of each fuel fired by the rate of each fuel burned. NR 440.19(7)(c)2.2. ASTM method D2015-96 or D5865-98 (solid fuels), D240-92 (liquid fuels) or D1826-94 (gaseous fuels), incorporated by reference in s. NR 440.17 (2) (a) 26., 66., 9. and 21., respectively, shall be used to determine the gross calorific values of the fuels. The method used to determine the calorific value of wood residue shall be approved by the department. NR 440.19(7)(c)3.3. Suitable methods shall be used to determine the rate of each fuel burned during each test period, and a material balance over the steam generating system shall be used to confirm the rate. NR 440.19(7)(d)(d) The owner or operator may use the following as alternatives to the reference methods and procedures in this subsection or in other subsections as specified: NR 440.19(7)(d)1.1. The emission rate (E) of particulate matter, SO2 and NOx may be determined by using the Fc factor, provided that the following procedure is used: E = CFc (100/%CO2)
where:
E is the emission rate of pollutant, ng/J (lb/million Btu)
C is the concentration of pollutant, ng/dscm (lb/dscf)
%CO2 is the carbon dioxide concentration, percent dry basis
Fc is the factor as determined in appropriate sections of Method 19
NR 440.19(7)(d)1.b.b. If and only if the average Fc factor in Method 19 is used to calculate E and either E is from 0.97 to 1.00 of the emission standard or the relative accuracy of a continuous emission monitoring system is from 17 to 20%, then 3 runs of Method 3 shall be used to determine the O2 and CO2 concentration according to the procedures in sub. (7) (b) 2. b., 4. b. or 5. b. Then if Fo (average of 3 runs), as calculated from the equation in Method 3B, is more than ±3% than the average Fo value, as determined from the average values of Fd and Fc in Method 19, that is, Foa = 0.209 (Fda/Fca), then the following procedure shall be followed: 1) When Fo is less than 0.97 Foa, then E shall be increased by that proportion under 0.97 Foa. For example, if Fo is 0.95 Foa, E shall be increased by 2%. This recalculated value shall be used to determine compliance with the emission standard.
2) When Fo is less than 0.97 Foa and when the average difference (d) between the continuous monitor minus the reference methods is negative, then E shall be increased by that proportion under 0.97 Foa. For example, if Fo is 0.95 Foa, E shall be increased by 2%. This recalculated value shall be used to determine compliance with the relative accuracy specification.
3) When Fo is greater than 1.03 Foa and when the average difference d is positive, then E shall be decreased by that proportion over 1.03 Foa. For example, if Fo is 1.05 Foa, E shall be decreased by 2%. This recalculated value shall be used to determine compliance with the relative accuracy specification.
NR 440.19(7)(d)2.2. For Method 5 or 5B, Method 17 may be used at facilities with or without wet FGD systems if the stack gas temperature at the sampling location does not exceed an average temperature of 160°C (320°F). The procedures of sections 2.1 and 2.3 of Method 5B may be used with Method 17 only if it is used after wet FGD systems. Method 17 may not be used after wet FGD systems if the effluent gas is saturated or laden with water droplets. NR 440.19(7)(d)3.3. Particulate matter and SO2 may be determined simultaneously with the Method 5 train provided that the following changes are made: NR 440.19(7)(d)3.a.a. The filter and impinger apparatus in sections 2.1.5 and 2.1.6 of Method 8 is used in place of the condenser (section 2.1.7) of Method 5. NR 440.19(7)(d)3.b.b. All applicable procedures in Method 8 for the determination of SO2, including moisture, are used. NR 440.19(7)(d)4.4. For Method 6, Method 6C may be used. Method 6A may also be used whenever Methods 6 and 3B data are specified to determine the SO2 emission rate, under the conditions in par. (d) 1. NR 440.19(7)(d)5.5. For Method 7, Method 7A, 7C, 7D or 7E may be used. If Method 7C, 7D or 7E is used, the sampling time for each run shall be at least 1 hour and the integrated sampling approach shall be used to determine the O2 concentration (%O2) for the emission rate correction factor. NR 440.19 HistoryHistory: Cr. Register, January, 1984, No. 337, eff. 2-1-84; am. (6) (c) 1., (7) (a) 2., 4. and 5., (7) (c), (e), (f) 2., 3. (intro.) and a., Register, September, 1986, No. 369, eff. 10-1-86; am. (1) (b), (2) (intro.), (5) (a) 1. and 2., (6) (c) 1. and (f) 5. a., (7) (a) 1. to 5., (b); (c) and (f) 3., Register, September, 1990, No. 417, eff. 10-1-90; r. and recr. (6) (c) 1., (g) (intro.) and (7), am. (6) (c) 3., (f) 1. to 3., 4. a. and 5. (intro.), Register, July, 1993, No. 451, eff. 8-1-93; am. (6) (f) 5. (intro.), a., (7) (b) 2. (intro.), Register, December, 1995, No. 480, eff. 1-1-96; CR 06-109: am. (2) (a), (6) (b) 2., (c) 3. a. to d., (f) 4. a., b. and f., 5. a. and b., (g) (intro.), (7) (b) 2. a. and b. and (c) 2. Register May 2008 No. 629, eff. 6-1-08. NR 440.20NR 440.20 Electric steam generating units for which construction is commenced after September 18, 1978. NR 440.20(1)(1) Applicability and designation of affected facility. NR 440.20(1)(a)(a) The affected facility to which this section applies is each electric utility steam generating unit: NR 440.20(1)(a)1.1. That is capable of combusting more than 73 megawatts (250 million Btu/hour) heat input of fossil fuel, either alone or in combination with any other fuel; and NR 440.20(1)(a)2.2. For which construction or modification is commenced after September 18, 1978. NR 440.20(1)(b)(b) Unless and until s. NR 440.50 extends the applicability of s. NR 440.50 to electric utility steam generators, this section applies to electric utility combined cycle gas turbines that are capable of combusting more than 73 megawatts (250 million Btu/hour) heat input of fossil fuel in the steam generator. Only emissions resulting from combustion of fuels in the steam generating unit are subject to this section. NR 440.20 NoteNote: The gas turbine emissions are subject to s. NR 440.50. NR 440.20(1)(c)(c) Any change to an existing fossil-fuel-fired steam generating unit to accommodate the use of combustible materials, other than fossil fuels, will not bring that unit under the applicability of this section. NR 440.20(1)(d)(d) Any change to an existing steam generating unit originally designed to fire gaseous or liquid fossil fuels, to accommodate the use of any other fuel (fossil or nonfossil) will not bring that unit under the applicability of this section. NR 440.20(2)(2) Definitions. As used in this section, terms not defined in this subsection have the meanings given in s. NR 440.02. NR 440.20(2)(a)(a) “24-hour period” means the period of time between 12:01 a.m. and 12:00 midnight. NR 440.20(2)(b)(b) “Anthracite” means coal that is classified as anthracite according to the ASTM Standard Specification for Classification of Coals by Rank, D388-99 (reapproved 2004), incorporated by reference in s. NR 440.17 (2) (a) 12. NR 440.20(2)(c)(c) “Available purchase power” means the lesser of the following: NR 440.20(2)(c)1.1. The sum of available system capacity in all neighboring companies. NR 440.20(2)(c)2.2. The sum of the rated capacities of the power interconnection devices between the principal company and all neighboring companies, minus the sum of the electric power load on these interconnections. NR 440.20(2)(c)3.3. The rated capacity of the power transmission lines between the power interconnection devices and the electric generating units (the unit in the principal company that has the malfunctioning flue gas desulfurization system and the unit or units in the neighboring company supplying replacement electrical power) less the electric power load on these transmission lines. NR 440.20(2)(d)(d) “Available system capacity” means the capacity determined by subtracting the system load and the system emergency reserves from the net system capacity. NR 440.20(2)(e)(e) “Boiler operating day” means a 24-hour period during which fossil fuel is combusted in a steam generating unit for the entire 24 hours. NR 440.20(2)(f)(f) “Coal refuse” means waste products of coal mining, physical coal cleaning, and coal preparation operations (e.g. culm, gob, etc.) containing coal, matrix material, clay, and other organic and inorganic material. NR 440.20(2)(g)(g) “Combined cycle gas turbine” means a stationary turbine combustion system where heat from the turbine exhaust gases is recovered by a steam generating unit. NR 440.20(2)(gr)(gr) “Duct burner” means a device that combusts fuel and that is placed in the exhaust duct from another source, such as a stationary gas turbine, internal combustion engine or kiln, to allow the firing of additional fuel to heat the exhaust gases before the exhaust gases enter a heat recovery steam generating unit. NR 440.20(2)(h)(h) “Electric utility combined cycle gas turbine” means any combined cycle gas turbine used for electric generation that is constructed for the purpose of supplying more than one-third of its potential electric output capacity and more than 25 MW electrical output to any utility power distribution system for sale. Any steam distribution system that is constructed for the purpose of providing steam to a steam-electric generator that would produce electrical power for sale is also considered in determining the electrical energy output capacity of the affected facility. NR 440.20(2)(i)(i) “Electric utility company” means the largest interconnected organization, business or governmental entity that generates electric power for sale (e.g., a holding company with operating subsidiary companies). NR 440.20(2)(j)(j) “Electric utility steam generating unit” means any steam electric generating unit that is constructed for the purpose of supplying more than one-third of its potential electric output capacity and more than 25 MW electrical output to any utility power distribution system for sale. Any steam supplied to a steam distribution system for the purpose of providing steam to a steam-electric generator that would produce electrical energy for sale is also considered in determining the electrical energy output capacity of the affected facility. NR 440.20(2)(k)1.1. The electric generation output of an affected facility with a malfunctioning flue gas desulfurization system cannot be reduced or electrical output must be increased because: NR 440.20(2)(k)1.a.a. All available system capacity in the principal company interconnected with the affected facility is being operated, and NR 440.20(2)(k)1.b.b. All available purchase power interconnected with the affected facility is being obtained, or NR 440.20(2)(k)2.2. The electric generation demand is being shifted as quickly as possible from an affected facility with a malfunctioning flue gas desulfurization system to one or more electrical generating units held in reserve by the principal company or by a neighboring company, or NR 440.20(2)(k)3.3. An affected facility with a malfunctioning flue gas desulfurization system becomes the only available unit to maintain a part or all of the principal company’s system emergency reserves and the unit is operated in spinning reserve at the lowest practical electric generation load consistent with not causing significant physical damage to the unit. If the unit is operated at a higher load to meet load demand, an emergency condition would not exist unless the conditions under subd. 1. apply. NR 440.20(2)(L)(L) “Fossil fuel” means natural gas, petroleum, coal, and any form of solid, liquid or gaseous fuel derived from such material for the purpose of creating useful heat. NR 440.20(2)(Lm)(Lm) “Gross output” means the gross useful work performed by the steam generated. For units generating only electricity, the gross useful work performed is the gross electrical output from the turbine or generator set. For cogeneration units, the gross useful work performed is the gross electrical output plus one half the useful thermal output (that is, steam delivered to an industrial process). NR 440.20(2)(m)(m) “Interconnected” means that 2 or more electric generating units are electrically tied together by a network of power transmission lines, and other power transmission equipment. NR 440.20(2)(n)(n) “Lignite” means coal that is classified as lignite A or B according to the ASTM Standard Specification for Classification of Coals by Rank, D388-99 (reapproved 2004), incorporated by reference in s. NR 440.17 (2) (a) 12. NR 440.20(2)(o)(o) “Neighboring company” means any one of those electric utility companies with one or more electric power interconnections to the principal company and which have geographically adjoining service areas. NR 440.20(2)(p)(p) “Net system capacity” means the sum of the net electric generating capability (not necessarily equal to rated capacity) of all electric generating equipment owned by an electric utility company (including steam generating units, internal combustion engines, gas turbines, nuclear units, hydroelectric units, and all other electric generating equipment) plus firm contractual purchases that are interconnected to the affected facility that has the malfunctioning flue gas desulfurization system. The electric generating capability of equipment under multiple ownership is prorated based on ownership unless the proportional entitlement to electric output is otherwise established by contractual arrangement. NR 440.20(2)(q)(q) “Potential combustion concentration” means the theoretical emissions (ng/J, lb/million Btu heat input) that would result from combustion of a fuel in an uncleaned state without emission control systems) and: NR 440.20(2)(r)(r) “Potential electrical output capacity” means 33% of the maximum design heat input capacity of the system generating unit (e.g., a steam generating unit with a 100-MW (340 million Btu/hr) fossil-fuel heat input capacity would have a 33-MW potential electrical output capacity). For electric utility combined cycle gas turbines the potential electrical output capacity is determined on the basis of the fossil-fuel firing capacity of the steam generator exclusive of the heat input and electrical power contribution by the gas turbine. NR 440.20(2)(s)(s) “Principal company” means the electric utility company which owns the affected facility. NR 440.20(2)(t)(t) “Resource recovery unit” means a facility that combusts more than 75% nonfossil fuel on a quarterly (calendar) heat input basis. NR 440.20(2)(u)(u) “Solid-derived fuel” means any solid, liquid or gaseous fuel derived from solid fuel for the purpose of creating useful heat and includes, but is not limited to, solvent refined coal, liquified coal and gasified coal. NR 440.20(2)(v)(v) “Spare flue gas desulfurization system module” means a separate system of sulfur dioxide emission control equipment capable of treating an amount of flue gas equal to the total amount of flue gas generated by an affected facility when operated at maximum capacity divided by the total number of nonspare flue gas desulfurization modules in the system. NR 440.20(2)(w)(w) “Spinning reserve” means the sum of the unutilized net generating capability of all units of the electric utility company that are synchronized to the power distribution system and that are capable of immediately accepting additional load. The electric generating capability of equipment under multiple ownership shall be prorated based on ownership unless the proportional entitlement to electric output is otherwise established by contractual arrangement. NR 440.20(2)(x)(x) “Steam generating unit” means any furnace, boiler, or other device used for combusting fuel for the purpose of producing steam including fossil-fuel-fired steam generators associated with combined cycle gas turbines but nuclear steam generators are not included. NR 440.20(2)(y)(y) “Subbituminous coal” means coal that is classified as subbituminous A, B or C according to the ASTM Standard Specification for Classification of Coals by Rank, D388-99 (reapproved 2004), incorporated by reference in s. NR 440.17 (2) (a) 12. NR 440.20(2)(z)(z) “System emergency reserves” means an amount of electric generating capacity equivalent to the rated capacity of the single largest electric generating unit in the electric utility company (including steam generating units, internal combustion engines, gas turbines, nuclear units, hydroelectric units and all other electric generating equipment) which is interconnected with the affected facility that has the malfunctioning flue gas desulfurization system. The electric generating capability of equipment under multiple ownership shall be prorated based on ownership unless the proportional entitlement to electric output is otherwise established by contractual arrangement. NR 440.20(2)(zm)(zm) “System load” means the entire electric demand of an electric utility company’s service area interconnected with the affected facility that has the malfunctioning flue gas desulfurization system plus firm contractual sales to other electric utility companies. Sales to other electric utility companies (e.g., emergency power) not on a firm contractual basis may also be included in the system load when no available system capacity exists in the electric utility company to which the power is supplied for sale. NR 440.20(3)(a)(a) On and after the date on which the performance test required to be conducted under s. NR 440.08 is completed, no owner or operator subject to the provisions of this section may cause to be discharged into the atmosphere from any affected facility any gases which contain particulate matter in excess of: NR 440.20(3)(a)1.1. 13 ng/J (0.03 lb/million Btu) heat input derived from the combustion of solid, liquid or gaseous fuel; NR 440.20(3)(a)2.2. One percent of the potential combustion concentration (99% reduction) when combusting solid fuel; and NR 440.20(3)(a)3.3. 30% of potential combustion concentration (70% reduction) when combusting liquid fuel.
