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NR 422.142 (4) RECORDKEEPING REQUIREMENTS. In addition to the applicable recordkeeping requirements in s. NR 439.04, the owner or operator of any lithographic printing press shall collect and record the applicable information specified in this subsection. The information shall be maintained at the facility for a minimum of 5 years and shall be made available to an authorized department representative at any time during normal working hours. The information required is all of the following:
(a) For a heatset web lithographic printing press using a control device, for each day of operation all of the following:
1. Control device Temperature monitoring data for the control device in accordance with sub. (3) (b) for each day of operation.
2. A log of the operating time for or record of any time when the control device, or control device monitoring equipment and is offline while the associated printing line or is in operation.
3. A maintenance log for the control device and control device monitoring equipment detailing all routine and non−routine maintenance performed and including the dates and duration of any outages.
SECTION 6. NR 422.142 (4) (a) 4. is created to read:
NR 422.142 (4) (a) 4. Annual inspection results for catalytic oxidizers.
SECTION 7. NR 422.142 (4) (d) and (e), and (5) (b) 1. and 2., (c), and (d) are amended to read:
  NR 422.142 (4) (d) For each blanket or roller wash cleaning solution prepared, the percent by weight VOC content or the VOC composite partial vapor pressure as applied and the vapor pressure of each VOC component.
  (e) For each month of operation, the volume of all blanket or roller wash cleaning solutions used which does that do not meet the emission limitations of sub. (2) (c) 1., as allowed under sub. (2) (c) 2.
  (5) (b) 1. Any facility with allowable VOC emissions from lithographic printing presses of 100 tons or more per year shall perform an emission test which that demonstrates compliance with sub. (2) (a) every 24 months. Each biennial test shall be performed within 90 days of the anniversary date of the initial emission test or an alternate date approved by the department. The testing exceptions listed in s. NR 439.075 (4) may apply to this test schedule.
2. Any facility with allowable VOC emissions from lithographic printing presses of less than 100 tons per year shall perform an initial emission test which that demonstrates compliance with sub. (2) (a) every 48 months. Each test shall be performed within 90 days of the anniversary date of the initial emission test.
  (c) The VOC content of lithographic inks, blanket or roller wash the as-applied fountain solutions and cleaning solutions shall be determined in accordance with s. NR 439.06 (3) (j) 422.143 (7) (c).
  (d) The vapor pressure of each VOC composite partial vapor pressure of each cleaning solution in blanket or roller wash shall be determined by ASTM D2879−10, incorporated by reference in s. NR 484.10 (39m) in accordance with s. NR 422.143 (7) (d).
SECTION 8. NR 422.143 (1) (a) is amended to read:
  NR 422.143 Lithographic printing — part 2. (1) APPLICABILITY. (a) Subsections (3) (b) and (c) and (4) apply This section applies to the owner or operator of a printing facility that operates a lithographic printing press in the county of Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington, or Waukesha if actual VOC emissions from all lithographic printing presses, including related lithographic cleaning activities and fountain solution use at the facility, before consideration of controls, equal or exceed 3 tons on a 12 consecutive month rolling basis. When determining the VOC emissions for applicability under this paragraph, the VOC emissions from the cleaning of electronic components of a lithographic printing press, pre−press and post−press cleaning operations and the use of janitorial supplies used to clean around a lithographic printing press are excluded. The VOC emissions from solvents used in cold cleaners are excluded for applicability purposes and meets the criteria in subd. (1) (a) 1. and 2.
SECTION 9. NR 422.143 (1) (a) (Note) is repealed.
SECTION 10. NR 422.143 (1) (a) 1. and 2. and (am) are created to read:
NR 422.143 (1) (a) 1. The facility has actual VOC emissions from all lithographic printing presses, including related lithographic cleaning activities and fountain solution use at the facility, before consideration of controls, equal to or greater than 3 tons on a 12 consecutive month rolling basis.
2. The facility meets any of the following criteria:
a. The facility is located in Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington, or Waukesha County.
b. The facility is constructed or modified on or after the effective date of this rule [LRB inserts date] and is located in Kewaunee or Manitowoc county.
c. The facility is located in any area designated as a moderate, serious, severe, or extreme ozone nonattainment area.
d. The facility is located in any area formerly designated as a moderate, serious, severe, or extreme ozone nonattainment area that has subsequently been redesignated to attainment, except for any facility subject to s. NR 422.142.
(am) When determining the VOC emissions for applicability under this paragraph, the VOC emissions shall include the emissions from the use of inks, fountain solutions, and cleaning solutions as defined in s. NR 422.02 (14m).
SECTION 11. NR 422.143 (1) (b) is repealed.
SECTION 12. NR 422.143 (1m) (f), (2) (intro.), and (a) are amended to read:
  NR 422.143 (1m) (f) A 40% VOC capture efficiency for automatic blanket or roller wash, as defined in s. NR 422.02 (7c), where the VOC composite partial vapor pressure of the automatic blanket or roller wash is less than 10 mm of Hg at 20°C (68°F).
  (2) EXEMPTIONS. The All of the following exemptions apply to lithographic printing operations in Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington and Waukesha counties affected by this section:
  (a) Up to 110 gallons of blanket or roller wash cleaning solutions, on a 12−consecutive month rolling basis, which that do not meet the low VOC composite partial vapor pressure or low VOC content requirements as stated in this section, are exempt from the requirements of this section.
SECTION 13. NR 422.143 (3) (c) (intro.) and 2. are consolidated, renumbered NR 422.143 (3) (c) and amended to read:
  NR 422.143 (3) (c) Blanket or roller washCleaning solutions. Except as provided in sub. (2) (a), no owner or operator of a lithographic printing press may use, or cause, allow, or permit the use of a blanket or roller wash unless: cleaning solution unless the cleaning solution
2. On and after February 1, 2012, for ultraviolet ink application equipment, the has a VOC content of the wash is less than 70% by weight or has a composite partial vapor pressure of less than or equal to 10 mm of Hg at 68ºF.
SECTION 14. NR 422.143 (3) (c) 1. is repealed.
SECTION 15. NR 422.143 (5) is renumbered NR 422.143 (5) (a) and NR 422.143 (5) (title) is amended to read:
NR 422.143 (5) (title) TEMPERATURE MONITORING REQUIREMENTS.
SECTION 16. NR 422.143 (5) (b) is created to read:
NR 422.143 (5) (b) The owner or operator of any lithographic printing press subject to the VOC control device requirements of sub. (3) (a) shall comply with all of the following monitoring requirements:
1. Install and operate continuous temperature monitoring and recording equipment that measures and records any of the following temperature of the control device at least once every 15 minutes:
a. The combustion chamber or minimum operating temperature for thermal oxidizers.
b. The catalytic bed inlet temperature for catalytic oxidizers.
2. Meet the instrument requirements in s. NR 439.055(3)(a) and (4) for the temperature monitoring devices.
3. Maintain the 3-hour average temperature at or above any of the following levels when the associated printing press is in operation:
a. 50ºF below the minimum operating temperature specified by the manufacturer for regenerative thermal oxidizers.
b. 50ºF below the average temperature measured during the most recent emission test that demonstrated compliance for all other type of oxidizers.
4. For catalytic oxidizers, inspect the catalyst bed material annually for general catalyst condition and any signs of potential catalyst depletion. The owner or operator shall also collect a representative sample of the catalyst from the catalytic oxidizer, in accordance with manufacturer's recommendations, and have it tested to evaluate the catalyst's capability to continue to function at or above the required control efficiency. An evaluation of the catalyst bed material shall be conducted whenever the results of the inspection indicate signs of potential catalyst depletion or poor catalyst condition based on manufacturer's recommendations, but not less than once per year.
5. Perform maintenance for the control devices in accordance with manufacturer's recommendations.
SECTION 17. NR 422.143 (6) (intro.) and (a) are amended to read:
NR 422.143 (6) RECORDKEEPING REQUIREMENTS. In addition to the applicable recordkeeping requirements in s. NR 439.04, the owner or operator of any lithographic printing press shall collect and record the applicable information specified in this subsection. The information shall be maintained at the facility for a minimum of 5 years and shall be made available to an authorized department representative at any time during normal working hours. The information required is all of the following:
(a) For a heatset web lithographic printing press using a control device, for each day of operation all of the following:
1. Control device Temperature monitoring data for the control device in accordance with s. NR 439.055 sub. (5) (b) 1. for each day of operation.
2. A log of the operating time for or record of any time when the control device, or control device monitoring equipment, and is offline while the associated printing line or is in operation.
3. A maintenance log for the control device and control device monitoring equipment detailing all routine and non−routine maintenance performed and including the dates and duration of any outages.
SECTION 18. NR 422.143 (6) (a) 4. is created to read:
NR 422.143 (6) (a) 4. Annual inspection results for catalytic oxidizers.
SECTION 19. NR 422.143 (6) (d) and (e) and (7) (a) and (b) 1. and 2. are amended to read:
  NR 422.143 (6) (d) For each batch of blanket or roller wash cleaning solution prepared, the percent by weight VOC content or the VOC composite partial vapor pressure, and the date and time the batch was for the cleaning solution prepared.
  (e) For each month of operation, the volume of all blanket or roller wash cleaning solutions used which does that do not meet either of the emission limitations in sub. (3) (c).
  (7) (a) The owner or operator of a heat-set web lithographic printing press shall demonstrate compliance with the appropriate destruction efficiency or emission rate in sub. (3) (a) by performing compliance emission tests on each control device. The initial emission tests shall be performed by the compliance deadline in sub. (8) (am) 1. or (b) 1. or 2. Each emission test shall follow the methods and procedures listed in s. NR 439.07. Method 18, 25 or 25A in 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (16), (19) and (20), shall be used to determine the VOC concentration at the sampling points. When determining the VOC concentration, the probe shall be heated during testing to at least the exhaust gas stream temperature.
  (b) 1. Any facility with allowable VOC emissions from lithographic printing presses of 100 tons or more per year shall perform an emission test which that demonstrates compliance with sub. (3) (a) every 24 months. Each biennial test shall be performed within 90 days of the anniversary date of the initial emission test or an alternate date approved by the department. The testing exceptions listed in s. NR 439.075 (4) may apply to this test schedule.
2. Any facility with allowable VOC emissions from lithographic printing presses of less than 100 tons per year shall perform an initial emission test which that demonstrates compliance with sub. (3) (a) every 48 months. Each test shall be performed within 90 days of the anniversary date of the initial emission test.
SECTION 20. NR 422.143 (7) (c) is renumbered (7) (c) (intro.) and amended to read:
  NR 422.143 (7) (c) The VOC content of heatset web, sheet−fed and cold set web lithographic inks the as-applied fountain solutions and cleaning solutions shall be determined in accordance with s. NR 439.06 (3) (j). by any of the following methods:
SECTION 21. NR 422.143 (7) (c) 1. and 2. and (d) are created to read:
  NR 422.143 (7) (c) 1. The method referred to in s. NR 439.06 (3) (j).
  2. If diluted prior to use, a calculation shall be performed for VOC content that combines the method referred in s. NR 439.06(3)(j) for the concentrated materials used to prepare the as-applied fountain solution or cleaning solution, and the proportions in which they are mixed to make the as-applied fountain solution or cleaning solution.
  (d) The VOC composite partial vapor pressure of each cleaning solution shall be determined by any of the following methods:
1. If diluted prior to use, calculate the VOC composite vapor pressure of the as-applied solvent by using the formula for "VOC composite vapor pressure" as follows:
a. Determine the identity and quantity of each compound in a blended organic solvent.
b. Determine the vapor pressure of each pure VOC component.
c. Calculate the VOC composite partial pressure of the solvent by using the formula for "VOC composite partial pressure." For the purpose of this calculation, the blended solvent shall be assumed to be an ideal solution where "Raoult's Law" applies. The partial vapor pressures of each compound at 68ºF shall be used in the formula. The VOC composite partial pressure shall be calculated as follows:
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