NR 466.07(3)(c)2.c.c. Calculate the as-applied organic HAP to solids ratio, Hsi, for all materials which do not meet the requirements of subd. 1., using Equation 5. NR 466.07(3)(d)(d) Demonstrate that the monthly average as-applied organic HAP content, HL, of all materials applied is less than 0.04 kg (0.04 lb) HAP per kg (lb) of material applied, using Equation 6. NR 466.07(3)(e)(e) Demonstrate that the monthly average as-applied organic HAP content, HS, is less than 0.20 kg (0.20 lb) HAP per kg (lb) solids applied using Equation 7. NR 466.07(3)(f)(f) Demonstrate that the total monthly organic HAP applied, H, as determined using Equation 8, is less than the calculated equivalent allowable organic HAP, Ha, as determined under sub. (6). NR 466.07(3)(g)(g) Operate a capture system and control device and demonstrate an overall organic HAP control efficiency of at least 95% for each month. If the affected source operates more than one capture system or more than one control device, and has only always-controlled work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7) or (9). If the affected source operates one or more never-controlled work stations or one or more intermittently-controllable work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance in accordance with the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer. NR 466.07(3)(h)(h) Operate a capture system and control device and limit the organic HAP emission rate to no more than 0.20 kg (0.20 lb) organic HAP emitted per kg (lb) solids applied as determined on a monthly average as-applied basis. If the affected source operates more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance following the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer. NR 466.07(3)(i)(i) Operate a capture system and control device and limit the organic HAP emission rate to no more than 0.04 kg (0.04 lb) organic HAP emitted per kg (lb) material applied as determined on a monthly average as-applied basis. If the affected source operates more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations, then the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance following the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer. NR 466.07(3)(j)(j) Operate a capture system and control device and limit the monthly organic HAP emissions to less than the allowable emissions as calculated in accordance with sub. (6). If the affected source operates more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance following the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer. NR 466.07(4)(4) Compliance demonstration for a solvent recovery device. NR 466.07(4)(a)(a) To demonstrate the overall organic HAP control efficiency required under sub. (3) (g), or the organic HAP emission limitation requirements in sub. (3) (h) to (j), each owner or operator using a solvent recovery device to control emissions shall do one of the following: NR 466.07(4)(a)1.1. Perform a liquid-liquid material balance for each month according to the following procedures: NR 466.07(4)(a)1.a.a. Measure the mass of each ink, coating, varnish, adhesive, primer, solvent and other material applied on the press or group of presses controlled by a common solvent recovery device during the month. NR 466.07(4)(a)1.b.b. If demonstrating compliance with sub. (2) (b), (c) or (d), determine the organic HAP content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (2) (b). NR 466.07(4)(a)1.c.c. Determine the volatile matter content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b). NR 466.07(4)(a)1.d.d. If demonstrating compliance with sub. (2) (c) or (d), determine the solids content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b). NR 466.07(4)(a)1.e.e. Install, calibrate, maintain and operate according to the manufacturer’s specifications, a device that indicates the cumulative amount of volatile matter recovered by the solvent recovery device on a monthly basis. The device shall be initially certified by the manufacturer to be accurate to within + 2.0%. NR 466.07(4)(a)1.g.g. Calculate the volatile matter collection and recovery efficiency, Rv, using Equation 9. (Equation 10)
NR 466.07(4)(a)1.i.i. If demonstrating compliance with sub. (2) (c), calculate the organic HAP emission rate based on solids applied, L, using Equation 11. NR 466.07(4)(a)1.j.j. If demonstrating compliance with sub. (2) (b), calculate the organic HAP emission rate based on material applied, S, using Equation 12. NR 466.07(4)(a)2.2. Conduct continuous emission monitoring of the control device, conduct an initial performance test of capture efficiency, and continuously monitor a site specific operating parameter to assure capture efficiency according to the following procedures: NR 466.07(4)(a)2.a.a. If demonstrating compliance with sub. (2) (b), (c) or (d), measure the mass of each ink, coating, varnish, adhesive, primer, solvent and other material applied on the press or group of presses controlled by a common control device during the month. NR 466.07(4)(a)2.b.b. If demonstrating compliance with sub. (2) (b), (c) or (d), determine the organic HAP content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (2) (b). NR 466.07(4)(a)2.c.c. Install continuous emission monitors to determine the total organic volatile matter mass flow rate at both the inlet to and the outlet from the control device, and calculate the percent efficiency (E) of the control device for each month. NR 466.07(4)(a)2.d.d. If demonstrating compliance with sub. (2) (c) or (d), determine the solids content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b). NR 466.07(4)(a)2.e.e. Install, calibrate, operate and maintain the instrumentation necessary to measure continuously the site-specific operating parameter established in accordance with s. NR 466.10 (6) whenever a product and packaging rotogravure or wide-web flexographic printing press is operated. NR 466.07(4)(a)2.g.g. Calculate the overall organic HAP control efficiency, (R), achieved for each month using Equation 13. NR 466.07(4)(a)2.h.h. If demonstrating compliance with sub. (2) (b), (c) or (d), calculate the organic HAP emitted during the month, H, for each month using Equation 14. (Equation 14)
NR 466.07(4)(a)2.i.i. If demonstrating compliance with sub. (2) (c), calculate the organic HAP emission rate based on solids applied, L, using Equation 15. NR 466.07(4)(a)2.j.j. If demonstrating compliance with sub. (2) (b), calculate the organic HAP emission rate based on material applied, S, using Equation 16. NR 466.07(4)(b)1.1. Under par. (a) 1., the affected source is in compliance with an emission limitation if one of the following is satisfied: NR 466.07(4)(b)1.a.a. The organic volatile matter collection and recovery efficiency, Rv, is 95% or greater. NR 466.07(4)(b)1.b.b. The organic HAP emission rate based on solids applied, L, is 0.20 kg (0.20 lb) organic HAP per kg (lb) solids applied or less. NR 466.07(4)(b)1.c.c. The organic HAP emission rate based on material applied, S, is 0.04 kg (0.04 lb) organic HAP per kg (lb) material applied or less. NR 466.07(4)(b)1.d.d. The organic HAP emitted during the month, H, is less than the calculated allowable organic HAP, Ha, as determined using sub. (6). NR 466.07(4)(b)2.2. Under par. (a) 2., the affected source is in compliance with an emission limitation if the capture system operating parameter is operated at an average value greater than or less than, as appropriate, the operating parameter value established in accordance with s. NR 466.10 (6) for each 3 hour period, and one of the following is satisfied: NR 466.07(4)(b)2.a.a. The organic volatile matter collection and recovery efficiency, Rv, is 95% or greater. NR 466.07(4)(b)2.b.b. The organic HAP emission rate based on solids applied, L, is 0.20 kg (0.20 lb) organic HAP per kg (lb) solids applied or less. NR 466.07(4)(b)2.c.c. The organic HAP emission rate based on material applied, S, is 0.04 kg (0.04 lb) organic HAP per kg (lb) material applied or less. NR 466.07(4)(b)2.d.d. The organic HAP emitted during the month, H, is less than the calculated allowable organic HAP, Ha, as determined using sub. (6). NR 466.07(5)(a)(a) To demonstrate the overall organic HAP control efficiency required under sub. (3) (g) or the organic HAP emission limitation requirements in sub. (3) (h) to (j), each owner or operator using an oxidizer to control emissions shall do one of the following: NR 466.07(5)(a)1.1. Conduct initial performance tests of capture efficiency and control device efficiency and continuously monitor capture system and control device operating parameters according to the following procedures: NR 466.07(5)(a)1.d.d. If demonstrating compliance with sub. (2) (b), (c) or (d), measure the mass of each ink, coating, varnish, adhesive, primer, solvent and other material applied on the press or group of presses controlled by a common solvent recovery device during the month. NR 466.07(5)(a)1.e.e. If demonstrating compliance with sub. (2) (b), (c) or (d), determine the organic HAP content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (2) (b). NR 466.07(5)(a)1.f.f. If demonstrating compliance with sub. (2) (c) or (d), determine the solids content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b). NR 466.07(5)(a)1.j.j. Install, calibrate, operate and maintain the instrumentation necessary to measure continuously the site-specific operating parameters established in accordance with s. NR 466.10 (5) and (6) whenever a product and packaging rotogravure or wide-web flexographic press is operating. NR 466.07(5)(a)2.2. Conduct continuous emission monitoring of the control device, conduct an initial performance test of capture efficiency, and continuously monitor a site specific operating parameter to assure capture efficiency in accordance with the requirements in sub. (4) (a) 2. NR 466.07(5)(b)1.1. Under par. (a) 1., the affected source is in compliance with an emission limitation if the oxidizer is operated such that the average operating parameter value is greater than the operating parameter value established in accordance with s. NR 466.10 (5) for each 3-hour period, and the capture system operating parameter is operated at an average value greater than or less than, as appropriate, the operating parameter value established in accordance with s. NR 466.10 (6) for each 3-hour period, and one of the following is satisfied: NR 466.07(5)(b)1.b.b. The organic HAP emission rate based on solids applied, L, is 0.20 kg (0.20 lb) organic HAP per kg (lb) solids applied or less. NR 466.07(5)(b)1.c.c. The organic HAP emission rate based on material applied, S, is 0.04 kg (0.04 lb) organic HAP per kg (lb) material applied or less. NR 466.07(5)(b)1.d.d. The organic HAP emitted during the month, H, is less than the calculated allowable organic HAP, Ha, as determined using sub. (6). NR 466.07(6)(6) Calculating monthly allowable hap emissions (Ha). Owners or operators shall calculate the monthly allowable HAP emissions, Ha, as required under sub. (3) (f), (4) (b) 1. d. or 2. d., or (5) (b) 1. d., according to the following procedures: NR 466.07(6)(a)(a) Determine the as-purchased mass of each ink, coating, varnish, adhesive, primer and other solids-containing material applied each month, Mi. NR 466.07(6)(b)(b) Determine the as-purchased solids content of each ink, coating, varnish, adhesive, primer and other solids-containing material applied each month, in accordance with s. NR 466.09 (3) (b), Csi. NR 466.07(6)(c)(c) Determine the as-purchased mass fraction of each ink, coating, varnish, adhesive, primer and other solids-containing material which was applied at 20% by weight or greater solids content, on an as-applied basis, Gi. NR 466.07(6)(d)(d) Determine the total mass of each solvent, diluent, thinner or reducer added to materials which were applied at less than 20% by weight solids content, on an as-applied basis, each month, MLj. NR 466.07(6)(e)(e) Calculate the monthly allowable HAP emissions, Ha, using Equation 17. NR 466.07(7)(7) Operating more than one capture system or control device, or one or more never-controlled or intermittently-controllable work stations. This subsection applies to owners or operators of product and packaging rotogravure or wide-web flexographic printing presses operating more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations. NR 466.07(7)(a)(a) The owner or operator of each solvent recovery system used to control one or more product and packaging rotogravure or wide-web flexographic presses for which the owner or operator chooses to perform a liquid-liquid material balance under sub. (4) (a) 1. shall determine the organic HAP emissions for those presses controlled by that solvent recovery system according to one of the following:
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Chs. NR 400-499; Environmental Protection – Air Pollution Control
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