Chapter NR 466

NR 466.06(4)(c)3. 3. Determine the volatile matter content, including water, of each ink, coating, varnish, adhesive, primer, solvent and other material used during the month following the procedure in s. NR 466.09 (3) (a).

NR 466.06(4)(d) (d) Compliance criteria.

NR 466.06(4)(d)1. 1. Under par. (a) 1., the affected source is in compliance for the month with the emission limitation if Re is at least 92% for that month.

NR 466.06(4)(d)2. 2. Under par. (a) 2., the affected source is in compliance for the month with the emission limitation if Re is at least 92% for that month, and the capture device is operated at an average value greater than, or less than, as appropriate, the operating parameter value established in accordance with s. NR 466.10 (6) for each 3-hour period.

NR 466.06(4)(d)3. 3. Under par. (b) 1., the affected source is in initial compliance with the emission limitation if Re is at least 92%. The affected source is in continuing compliance with the emission limitation if par. (b) 1. e. and either par. (b) 1. f. or g. are satisfied.

NR 466.06(4)(d)4. 4. Under par. (b) 2., the affected source is in compliance for the month with the emission limitation if the criteria of subd. 2. are satisfied.

NR 466.06(4)(d)5. 5. Under par. (c), the affected source is in compliance for the month with the emission limitation if the mass of organic HAP used does not exceed 8% of the mass of volatile matter used.

NR 466.06 History History: Cr. Register, March, 2000, No. 531, eff. 4-1-00.

NR 466.07 NR 466.07 Standards: product and packaging rotogravure and wide-web flexographic printing.

NR 466.07(1) (1) Compliance dates. Each owner or operator of any product and packaging rotogravure or wide-web flexographic printing affected source that is subject to the requirements of this chapter shall comply with this section on and after the compliance dates as specified in s. NR 466.08.

NR 466.07(2) (2) Emission limitations. The owner or operator of each product and packaging rotogravure or wide-web flexographic printing affected source shall limit organic HAP emissions to no more than any one of the following:

NR 466.07(2)(a) (a) Five percent of the organic HAP applied for the month.

NR 466.07(2)(b) (b) Four percent of the mass of inks, coatings, varnishes, adhesives, primers, solvents, reducers, thinners and other materials applied for the month.

NR 466.07(2)(c) (c) Twenty percent of the mass of solids applied for the month.

NR 466.07(2)(d) (d) A calculated equivalent allowable mass based on the organic HAP and solids contents of the inks, coatings, varnishes, adhesives, primers, solvents, reducers, thinners and other materials applied for the month.

NR 466.07(3) (3) Compliance methods. The owner or operator of each product and packaging rotogravure or wide-web flexographic printing affected source shall demonstrate compliance with sub. (2) according to one of the following procedures:

NR 466.07(3)(a) (a) Demonstrate that each ink, coating, varnish, adhesive, primer, solvent, diluent, reducer, thinner and other material applied during the month contains no more than 0.04 weight-fraction organic HAP, on an as-purchased basis, as determined in accordance with s. NR 466.09 (2) (b).

NR 466.07(3)(b) (b) Demonstrate that each ink, coating, varnish, adhesive, primer and other solids-containing material applied during the month contains no more than 0.04 weight-fraction organic HAP, on a monthly average as-applied basis, as determined in accordance with the following procedures:

NR 466.07(3)(b)1. 1. Determine the organic HAP content of each ink, coating, varnish, adhesive, primer, solvent, diluent, reducer, thinner and other material applied on an as-purchased basis in accordance with s. NR 466.09 (2) (b).

NR 466.07(3)(b)2. 2. Calculate the monthly average as-applied organic HAP content (Cahi ) of each ink, coating, varnish, adhesive, primer and other solids-containing material using Equation 3.

(Equation 3)

NR 466.07(3)(c) (c) Demonstrate that each ink, coating, varnish, adhesive, primer and other solids-containing material applied, contains no more than one of the following:

NR 466.07(3)(c)1. 1. 0.04 weight-fraction organic HAP on a monthly average as-applied basis, when determined in accordance with par. (b).

NR 466.07(3)(c)2. 2. 0.20 kg (0.20 lb) of organic HAP per kg (lb) of solids applied, on a monthly average as-applied basis, when determined in accordance with the following procedures:

NR 466.07(3)(c)2.a. a. Determine the as-applied solids content following the procedure in s. NR 466.09 (3) (b) of all materials which do not meet the requirements of subd.1.

NR 466.07(3)(c)2.b. b. Calculate the monthly average as-applied solids content of materials which are reduced, thinned or diluted prior to application, using Equation 4.

NR 466.07(3)(c)2.c. c. Calculate the as-applied organic HAP to solids ratio, Hsi, for all materials which do not meet the requirements of subd. 1., using Equation 5.

(Equation 5)

NR 466.07(3)(d) (d) Demonstrate that the monthly average as-applied organic HAP content, HL, of all materials applied is less than 0.04 kg (0.04 lb) HAP per kg (lb) of material applied, using Equation 6.

  (Equation 6)

NR 466.07(3)(e) (e) Demonstrate that the monthly average as-applied organic HAP content, HS, is less than 0.20 kg (0.20 lb) HAP per kg (lb) solids applied using Equation 7.

  (Equation 7)

NR 466.07(3)(f) (f) Demonstrate that the total monthly organic HAP applied, H, as determined using Equation 8, is less than the calculated equivalent allowable organic HAP, Ha, as determined under sub. (6).

  (Equation 8)

NR 466.07(3)(g) (g) Operate a capture system and control device and demonstrate an overall organic HAP control efficiency of at least 95% for each month. If the affected source operates more than one capture system or more than one control device, and has only always-controlled work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7) or (9). If the affected source operates one or more never-controlled work stations or one or more intermittently-controllable work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance in accordance with the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer.

NR 466.07(3)(h) (h) Operate a capture system and control device and limit the organic HAP emission rate to no more than 0.20 kg (0.20 lb) organic HAP emitted per kg (lb) solids applied as determined on a monthly average as-applied basis. If the affected source operates more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance following the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer.

NR 466.07(3)(i) (i) Operate a capture system and control device and limit the organic HAP emission rate to no more than 0.04 kg (0.04 lb) organic HAP emitted per kg (lb) material applied as determined on a monthly average as-applied basis. If the affected source operates more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations, then the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance following the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer.

NR 466.07(3)(j) (j) Operate a capture system and control device and limit the monthly organic HAP emissions to less than the allowable emissions as calculated in accordance with sub. (6). If the affected source operates more than one capture system, more than one control device, one or more never-controlled work stations, or one or more intermittently-controllable work stations, the owner or operator shall demonstrate compliance in accordance with the provisions of sub. (7). Otherwise, the owner or operator shall demonstrate compliance following the procedure in sub. (4) when emissions from the affected source are controlled by a solvent recovery device or the procedure in sub. (5) when emissions are controlled by an oxidizer.

NR 466.07(4) (4) Compliance demonstration for a solvent recovery device.

NR 466.07(4)(a) (a) To demonstrate the overall organic HAP control efficiency required under sub. (3) (g), or the organic HAP emission limitation requirements in sub. (3) (h) to (j), each owner or operator using a solvent recovery device to control emissions shall do one of the following:

NR 466.07(4)(a)1. 1. Perform a liquid-liquid material balance for each month according to the following procedures:

NR 466.07(4)(a)1.a. a. Measure the mass of each ink, coating, varnish, adhesive, primer, solvent and other material applied on the press or group of presses controlled by a common solvent recovery device during the month.

NR 466.07(4)(a)1.b. b. If demonstrating compliance with sub. (2) (b), (c) or (d), determine the organic HAP content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (2) (b).

NR 466.07(4)(a)1.c. c. Determine the volatile matter content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b).

NR 466.07(4)(a)1.d. d. If demonstrating compliance with sub. (2) (c) or (d), determine the solids content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b).

NR 466.07(4)(a)1.e. e. Install, calibrate, maintain and operate according to the manufacturer’s specifications, a device that indicates the cumulative amount of volatile matter recovered by the solvent recovery device on a monthly basis. The device shall be initially certified by the manufacturer to be accurate to within + 2.0%.

NR 466.07(4)(a)1.f. f. Measure the amount of volatile matter recovered for the month.

NR 466.07(4)(a)1.g. g. Calculate the volatile matter collection and recovery efficiency, Rv, using Equation 9.

NR 466.07(4)(a)1.h. h. If demonstrating compliance with sub. (2) (b), (c) or (d), calculate the organic HAP emitted during the month, H, using Equation 10.

  (Equation 10)

NR 466.07(4)(a)1.i. i. If demonstrating compliance with sub. (2) (c), calculate the organic HAP emission rate based on solids applied, L, using Equation 11.

NR 466.07(4)(a)1.j. j. If demonstrating compliance with sub. (2) (b), calculate the organic HAP emission rate based on material applied, S, using Equation 12.

ú

û

ù

ê

ë

é

NR 466.07(4)(a)2. 2. Conduct continuous emission monitoring of the control device, conduct an initial performance test of capture efficiency, and continuously monitor a site specific operating parameter to assure capture efficiency according to the following procedures:

NR 466.07(4)(a)2.a. a. If demonstrating compliance with sub. (2) (b), (c) or (d), measure the mass of each ink, coating, varnish, adhesive, primer, solvent and other material applied on the press or group of presses controlled by a common control device during the month.

NR 466.07(4)(a)2.b. b. If demonstrating compliance with sub. (2) (b), (c) or (d), determine the organic HAP content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (2) (b).

NR 466.07(4)(a)2.c. c. Install continuous emission monitors to determine the total organic volatile matter mass flow rate at both the inlet to and the outlet from the control device, and calculate the percent efficiency (E) of the control device for each month.

NR 466.07(4)(a)2.d. d. If demonstrating compliance with sub. (2) (c) or (d), determine the solids content of each ink, coating, varnish, adhesive, primer, solvent and other material applied during the month following the procedure in s. NR 466.09 (3) (b).

NR 466.07(4)(a)2.e. e. Install, calibrate, operate and maintain the instrumentation necessary to measure continuously the site-specific operating parameter established in accordance with s. NR 466.10 (6) whenever a product and packaging rotogravure or wide-web flexographic printing press is operated.

NR 466.07(4)(a)2.f. f. Determine the capture efficiency (F) in accordance with s. NR 466.09 (5) and (6).

NR 466.07(4)(a)2.g. g. Calculate the overall organic HAP control efficiency, (R), achieved for each month using Equation 13.

NR 466.07(4)(a)2.h. h. If demonstrating compliance with sub. (2) (b), (c) or (d), calculate the organic HAP emitted during the month, H, for each month using Equation 14.

  (Equation 14)

NR 466.07(4)(a)2.i. i. If demonstrating compliance with sub. (2) (c), calculate the organic HAP emission rate based on solids applied, L, using Equation 15.

(Equation 15)

NR 466.07(4)(a)2.j. j. If demonstrating compliance with sub. (2) (b), calculate the organic HAP emission rate based on material applied, S, using Equation 16.

ú

û

ù

ê

ë

é

NR 466.07(4)(b) (b)

NR 466.07(4)(b)1. 1. Under par. (a) 1., the affected source is in compliance with an emission limitation if one of the following is satisfied:

NR 466.07(4)(b)1.a. a. The organic volatile matter collection and recovery efficiency, Rv, is 95% or greater.

NR 466.07(4)(b)1.b. b. The organic HAP emission rate based on solids applied, L, is 0.20 kg (0.20 lb) organic HAP per kg (lb) solids applied or less.

NR 466.07(4)(b)1.c. c. The organic HAP emission rate based on material applied, S, is 0.04 kg (0.04 lb) organic HAP per kg (lb) material applied or less.

NR 466.07(4)(b)1.d. d. The organic HAP emitted during the month, H, is less than the calculated allowable organic HAP, Ha, as determined using sub. (6).

NR 466.07(4)(b)2. 2. Under par. (a) 2., the affected source is in compliance with an emission limitation if the capture system operating parameter is operated at an average value greater than or less than, as appropriate, the operating parameter value established in accordance with s. NR 466.10 (6) for each 3 hour period, and one of the following is satisfied:

NR 466.07(4)(b)2.a. a. The organic volatile matter collection and recovery efficiency, Rv, is 95% or greater.

NR 466.07(4)(b)2.b. b. The organic HAP emission rate based on solids applied, L, is 0.20 kg (0.20 lb) organic HAP per kg (lb) solids applied or less.

NR 466.07(4)(b)2.c. c. The organic HAP emission rate based on material applied, S, is 0.04 kg (0.04 lb) organic HAP per kg (lb) material applied or less.

NR 466.07(4)(b)2.d. d. The organic HAP emitted during the month, H, is less than the calculated allowable organic HAP, Ha, as determined using sub. (6).

NR 466.07(5) (5) Compliance demonstration for an oxidizer.

NR 466.07(5)(a) (a) To demonstrate the overall organic HAP control efficiency required under sub. (3) (g) or the organic HAP emission limitation requirements in sub. (3) (h) to (j), each owner or operator using an oxidizer to control emissions shall do one of the following:

NR 466.07(5)(a)1. 1. Conduct initial performance tests of capture efficiency and control device efficiency and continuously monitor capture system and control device operating parameters according to the following procedures:

NR 466.07(5)(a)1.a. a. Determine the oxidizer destruction efficiency (E) using the procedure in s. NR 466.09 (4).

NR 466.07(5)(a)1.b. b. Determine the capture system capture efficiency (F) in accordance with s. NR 466.09 (5) and (6).