Chapter NR 417

Register October 1999 No. 526

Chapter NR 417

CONTROL OF SULFUR EMISSIONS

NR 417.01   Applicability; purpose.

NR 417.02   Definitions.

NR 417.03   General limitations.

NR 417.05   Petroleum refineries.

NR 417.06   Total reduced sulfur limitations.

NR 417.07   Statewide sulfur dioxide emission limitations.

Ch. NR 417 Note Note: Corrections made under s. 13.93 (2m) (b) 7., Stats., Register, December, 1996, No. 492.

NR 417.01 NR 417.01 Applicability; purpose.

NR 417.01(1) (1) Applicability. This chapter applies to all air contaminant sources which emit sulfur dioxide or other sulfur compounds and to their owners and operators.

NR 417.01(2) (2) Purpose. This chapter is adopted under ss. 285.11, 285.13 and 285.17, Stats., to categorize sulfur dioxide and sulfur compound air contaminant sources and to establish emission limitations for these sources in order to protect air quality.

NR 417.01 History History: Cr. Register, September, 1986, No. 369, eff. 10-1-86; am. (1), Register, May, 1992, No. 437, eff. 6-1-92; am. (2), Register, October, 1999, No. 526, eff. 11-1-99.

NR 417.02 NR 417.02 Definitions. The definitions contained in ch. NR 400 apply to the terms used in this chapter. In addition, the following definitions apply to the terms used in this chapter:

NR 417.02(1) (1) “Equivalent air-dried kraft pulp” means pulp production which produces a loading of black liquor solids to the recovery furnace equivalent to that loading produced with kraft pulp.

NR 417.02 History History: Cr. Register, September, 1986, No. 369, eff. 10-1-86; (1) renum. from NR 400.02 (37), Register, May, 1992, No. 437, eff. 6-1-92; am. (intro.), Register, December, 1995, No. 480, eff. 1-1-96.

NR 417.03 NR 417.03 General limitations. No person may cause, allow or permit emission of sulfur or sulfur compounds into the ambient air which substantially contribute to the exceeding of an air standard or cause air pollution. The limitation on total reduced sulfur from pulping operations is specified in s. NR 417.06.

NR 417.03 History History: Renum. from NR 154.12 (1) and am. Register, September, 1986, No. 369, eff. 10-1-86; renum. from NR 417.025, Register, August, 1996, No. 488, eff. 9-1-96.

NR 417.05 NR 417.05 Petroleum refineries. No person may cause, allow or permit the release into the atmosphere or the burning of any fuel gas in an incinerator-waste heat boiler or process heater which contains greater than 0.10 grains of hydrogen sulfide (H2S) per dry cubic foot at standard conditions (0.23 grams per dry cubic meter at standard conditions) unless the gases resulting from combustion are treated in a manner which prevents the release of sulfur dioxide to the atmosphere as effectively as controlling the concentration of H2S in the fuel gas being burned.

NR 417.05 History History: Renum. from NR 154.12 (3), Register, September, 1986, No. 369, eff. 10-1-86; am. Register, May, 1992, No. 437, eff. 6-1-92.

NR 417.06 NR 417.06 Total reduced sulfur limitations. No person may cause, allow or permit emission into the ambient air of total reduced sulfur (TRS) in excess of the limitations in this section. All emission standards in this section are based on average daily emissions.

NR 417.06(1) (1) The emission of TRS from all recovery furnace stacks may not exceed 0.50 pound of reduced sulfur compounds (as sulfur) per equivalent ton of air-dried kraft pulp, or from each recovery furnace stack 17.5 ppm, expressed as hydrogen sulfide on a dry gas basis, whichever is the more restrictive. New direct sources shall meet such other limit of TRS that proves to be reasonably attainable utilizing the latest in design of recovery furnace equipment, controls, and procedures.

NR 417.06(2) (2) Noncondensibles from digesters and multiple-effect evaporators shall be treated to reduce the emission of TRS equal to the reduction achieved by thermal oxidation in a lime kiln.

NR 417.06 History History: Renum. from NR 154.18 (2), Register, September, 1986, No. 369, eff. 10-1-86; am. (intro.) and (1), Register, May, 1992, No. 437, eff. 6-1-92; am. (1) and (2), r. (3), Register, December, 1995, No. 480, eff. 1-1-96.

NR 417.07 NR 417.07 Statewide sulfur dioxide emission limitations.

NR 417.07(1) (1) Applicability. This section applies to any direct source of sulfur dioxide, with the following exceptions:

NR 417.07(1)(a) (a) Any direct source which is subject to emission limitations specified in ch. NR 418.

NR 417.07(1)(b) (b) Any direct source which is subject to an emission limitation for sulfur dioxide, imposed by statute, rule, permit, order or plan approval, which is more restrictive than an emission limitation under sub. (2) or (3).

NR 417.07(2) (2) Emission limits for existing sources. Except as provided under sub. (5) or (8), no person may cause, allow or permit sulfur dioxide to be emitted to the ambient air from any direct source constructed on or before February 1, 1985, in amounts greater than those specified in this subsection.

NR 417.07(2)(a) (a) All steam generating units and other fuel burning equipment firing solid fossil fuel, alone or in combination with fuel burning equipment firing other fuels, at a facility which has a total heat input capacity on solid fossil fuel of greater than or equal to 250 million Btu per hour, may not emit from any stack more than 3.2 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(2)(b) (b) Any steam generating unit or other fuel burning equipment firing solid fossil fuel at a facility which has a total heat input capacity on solid fossil fuel of less than 250 million Btu per hour may not emit from any stack more than 5.5 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(2)(c) (c) Any steam generating unit or other fuel burning equipment firing residual fuel oil at a facility which has a total heat input capacity on residual fuel oil of greater than or equal to 250 million Btu per hour may not emit from any stack more than 1.5 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(2)(d) (d) Any steam generating unit or other fuel burning equipment firing residual fuel oil at a facility which has a total heat input capacity on residual fuel oil of less than 250 million Btu per hour may not emit from any stack more than 3.0 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(2)(e) (e) Any kraft mill producing pulp may not emit more than 10.0 pounds of sulfur dioxide per ton of air dried unbleached pulp from all process sources at the kraft mill. Process sources do not include equipment which derives more than 50% of its annual heat input from solid fossil fuel, residual fuel oil, wood or wood waste.

NR 417.07(2)(f) (f) Any sulfite mill producing pulp may not emit more than 20.0 pounds of sulfur dioxide per ton of air dried unbleached pulp from all process sources at the sulfite mill. Process sources do not include equipment which derives more than 50% of its annual heat input from solid fossil fuel, residual fuel oil, wood or wood waste.

NR 417.07(2)(g) (g) Any petroleum refinery shall comply with the following emission limitations:

NR 417.07(2)(g)1. 1. The sulfur dioxide emissions from any process heater firing residual fuel oil may not exceed 0.80 pounds of sulfur dioxide per million Btu heat input from the process heater.

NR 417.07(2)(g)2. 2. The sulfur dioxide emissions from any stack serving any fuel burning equipment firing residual fuel oil may not exceed 0.80 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(2)(g)3. 3. The sulfur dioxide emissions from any Claus sulfur recovery plant may not exceed 6,743 pounds of sulfur dioxide in any 24-hour period or 843 pounds of sulfur dioxide in any 3-hour period.

NR 417.07(2)(g)4. 4. The sulfur dioxide emissions from all other process units may not exceed 1,035 pounds of sulfur dioxide in any 1-hour period.

NR 417.07(3) (3) Emission limits for new sources. No person may cause, allow or permit sulfur dioxide to be emitted to the ambient air from any direct source constructed after February 1, 1985 in amounts greater than those specified in this subsection.

NR 417.07(3)(a) (a) Any steam generating unit or other fuel burning equipment firing solid fossil fuel may not emit from any stack more than 3.2 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(3)(b) (b) Any steam generating unit or other fuel burning equipment firing residual fuel oil may not emit from any stack more than 1.5 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(3)(c) (c) Any kraft mill producing pulp may not emit more than 10.0 pounds of sulfur dioxide per ton of air dried unbleached pulp from all process sources at the kraft mill. Process sources do not include equipment which derives more than 50% of its annual heat input from solid fossil fuel, residual fuel oil, wood or wood waste.

NR 417.07(3)(d) (d) Any sulfite mill producing pulp may not emit more than 20.0 pounds of sulfur dioxide per ton of air dried unbleached pulp from all process sources at the sulfite mill. Process sources do not include equipment which derives more than 50% of its annual heat input from solid fossil fuel, residual fuel oil, wood or wood waste.

NR 417.07(3)(e) (e) Any petroleum refinery shall comply with the following emission limitations:

NR 417.07(3)(e)1. 1. The sulfur dioxide emissions from any process heater firing residual fuel oil may not exceed 1.5 pounds of sulfur dioxide per million Btu heat input from the process heater.

NR 417.07(3)(e)2. 2. The sulfur dioxide emissions from any stack serving any fuel burning equipment firing residual fuel oil may not exceed 1.5 pounds of sulfur dioxide per million Btu heat input.

NR 417.07(3)(e)3. 3. The sulfur dioxide emissions from any Claus sulfur recovery plant may not exceed:

NR 417.07(3)(e)3.a. a. 0.025% by volume of sulfur dioxide at zero percent oxygen on a dry basis, if emissions are controlled by an oxidation control system or a reduction control system followed by incineration.

NR 417.07(3)(e)3.b. b. 0.030% by volume of reduced sulfur compounds and 0.0010% by volume of hydrogen sulfide calculated as sulfur dioxide at zero percent oxygen on a dry basis, if emissions are controlled by a reduction control system not followed by incineration.

NR 417.07(4) (4) More restrictive emission limits. The department may require a source to meet a more restrictive emission limitation than an applicable emission limitation provided under sub. (2) or (3) if the department determines that a more restrictive emission limitation is required to ensure that the source will not cause or exacerbate a violation of an ambient air quality standard or air increment for sulfur dioxide.

NR 417.07(5) (5) Alternate emission limits. The department may grant an alternate emission limitation to a source which is subject to an emission limitation in sub. (2) (a), (c), (e), (f) or (g) if the following conditions are met:

NR 417.07(5)(a) (a) The owner or operator of the source submits a written request for an alternate emission limitation which outlines the specific conditions or special circumstances which prevent the source from complying with the applicable emission limitation in sub. (2) and which contains a proposed alternate emission limitation for the source.

NR 417.07(5)(b) (b) The owner or operator of the source demonstrates that the proposed alternate emission limitation will not delay attainment or prevent maintenance of an ambient air quality standard for sulfur dioxide, as demonstrated by air quality modeling acceptable to the department.

NR 417.07(5)(c) (c) If the source is subject to the emission limitation in sub. (2) (a) or (c), the proposed alternate emission limitation may not exceed 5.5 pounds of sulfur dioxide per million Btu heat input for any fuel burning equipment firing solid fossil fuel; or 3.0 pounds of sulfur dioxide per million Btu heat input for any fuel burning equipment firing residual fuel oil. The alternate emission limitation of 5.5 pounds of sulfur dioxide per million Btu heat input for solid fossil fuel burning equipment may be calculated on a 30-day rolling average for a source, if there is one or more other sulfur dioxide emission limitations applicable to the source which would assure the attainment and maintenance of the ambient air quality standards for sulfur dioxide.

NR 417.07(5)(e) (e) The owner or operator of the source demonstrates that there is a substantial cost difference between the costs required for the source’s compliance with the applicable emission limitation in sub. (2) and the costs required for the source’s compliance with the proposed alternate emission limitation.