NR 666.023 History
History: CR 05-032: cr.
Register July 2006 No. 607, eff. 8-1-06;
CR 16-007: am. (2)
Register July 2017 No. 739, eff. 8-1-17.
NR 666.070
NR 666.070 Applicability and requirements. NR 666.070(1)(1)
This subchapter applies to recyclable materials that are reclaimed to recover economically significant amounts of gold, silver, platinum, palladium, iridium, osmium, rhodium, ruthenium or any combination of these.
NR 666.070(2)
(2) Persons who generate, transport or store recyclable materials that are regulated under this subchapter are subject to all of the following requirements:
NR 666.070 Note
Note: Hazardous waste transportation licenses are not required for transporting only recyclable materials regulated under this subchapter.
NR 666.070(3)
(3) Persons who store recycled materials that are regulated under this subchapter shall keep all of the following records to document that they are not accumulating these materials speculatively (as defined in s.
NR 661.0001 (3)):
NR 666.070(3)(a)
(a) Records showing the volume of these materials stored at the beginning of the calendar year.
NR 666.070(3)(b)
(b) The amount of these materials generated or received during the calendar year.
NR 666.070(3)(c)
(c) The amount of materials remaining at the end of the calendar year.
NR 666.070(4)
(4) Recyclable materials that are regulated under this subchapter that are accumulated speculatively (as defined in s.
NR 661.0001 (3)) are subject to all applicable provisions of chs.
NR 662 to
665,
667 and
670.
NR 666.070 History
History: CR 05-032: cr.
Register July 2006 No. 607, eff. 8-1-06;
CR 19-082: am. (2) (c), (3) (intro.), (4)
Register August 2020 No. 776, eff. 9-1-20.
NR 666.080
NR 666.080 Applicability and requirements. NR 666.080(1)(1)
A person that generates, collects, transports, stores or regenerates lead
-acid batteries for reclamation purposes may be exempt from certain hazardous waste management requirements. Use the following table to determine which requirements apply
. Alternatively
, spent lead
-acid batteries may be managed under ch.
NR 673, the “Universal Waste” rule.
NR 666.080 Note
Note: In addition to the requirements under this subchapter or ch.
NR 673, s.
287.18, Stats., applies to persons who sell lead
-acid batteries.
-
See PDF for table 
NR 666.080(2)
(2) If I store spent lead-acid batteries before I reclaim them but not through regeneration, which requirements apply? The requirements of this subsection apply to you if you store spent lead-acid batteries before you reclaim them, but you don't reclaim them through regeneration. The requirements are slightly different depending on your hazardous waste license status.
NR 666.080(2)(a)
(a) If your facility has an interim license, you shall comply with all of the following:
NR 666.080(2)(b)
(b) If your facility has an operating license, you shall comply with all of the following:
NR 666.080 History
History: CR 05-032: cr.
Register July 2006 No. 607, eff. 8-1-06;
CR 16-007: am. (1) (a) to (e), cr. (2)
Register July 2017 No. 739, eff. 8-1-17;
CR 19-082: r. and recr. (1), cr. (2) (a) 8., (b) 8.
Register August 2020 No. 776, eff. 9-1-20; correction in (1) (d), (f) to (j) made under s.
35.17, Stats.,
Register August 2020 No. 776.
Subch. H of ch. NR 666 Note
Note: This subchapter is similar to federal regulations contained in
40 CFR part 266 subpart H, revised as of July 1, 2003.
NR 666.100(1)(1)
The regulations of this subchapter apply to hazardous waste burned or processed in a boiler or industrial furnace (as defined in s.
NR 660.10) irrespective of the purpose of burning or processing, except as provided by subs.
(2),
(3),
(4),
(7) and
(8). In this subchapter, the term “burn" means burning for energy recovery or destruction, or processing for materials recovery or as an ingredient. The emissions standards of ss.
NR 666.104,
666.105,
666.106 and
666.107 apply to facilities operating under an interim license or under a license as specified in ss.
NR 666.102 and
666.103.
NR 666.100(2)(a)(a) Except as provided by pars.
(b),
(c), and
(d), the standards of this subchapter do not apply to a new hazardous waste boiler or industrial furnace unit that becomes subject to hazardous waste license requirements after October 12, 2005; or no longer apply when an affected source demonstrates compliance with the maximum achievable control technology (MACT) requirements of
40 CFR part 63, subpart EEE, by conducting a comprehensive performance test and submitting to the department a notification of compliance under
40 CFR 63.1207(j) and 63.1210(d) documenting compliance with
40 CFR part 63, subpart EEE. Nevertheless, even after this demonstration of compliance with the MACT standards, hazardous waste license conditions that were based on the standards of this chapter shall continue to be in effect until the conditions are removed from the license or the license is terminated or revoked, unless the license expressly provides otherwise.
NR 666.100(2)(b)1.
1. If you elect to comply with s.
NR 670.235 (1) (a) 1. to minimize emissions of toxic compounds from startup, shutdown and malfunction events, s.
NR 666.102 (5) (a) requiring operations in accordance with the operating requirements specified in the license at all times that hazardous waste is in the unit, and s.
NR 666.102 (5) (b) 3. requiring compliance with the emission standards and operating requirements during startup and shutdown if hazardous waste is in the combustion chamber, except for particular hazardous wastes. These provisions apply only during startup, shutdown and malfunction events.
NR 666.100(2)(c)
(c) If an owner or operator of a boiler or hydrochloric acid production furnace that is an area source under
40 CFR 63.2 and the owner or operator elects not to comply with the emission standards under
40 CFR 63.1216,
63.1217, and
63.1218 for particulate matter, semi-volatile and low volatile metals and total chlorine, the owner or operator remains subject to:
NR 666.100(2)(d)
(d) The particulate matter standard of s.
NR 666.105 remains in effect for boilers that elect to comply with the alternative to the particulate matter standard under
40 CFR 63.1216(e) and 63.1217(e).
NR 666.100(3)
(3) The following hazardous wastes and facilities are not subject to regulation under this subchapter:
NR 666.100(3)(a)
(a) Used oil burned for energy recovery that is also a hazardous waste solely because it exhibits a characteristic of hazardous waste identified in subch.
C of ch. NR 661. Such used oil is subject to regulation under ch.
NR 679.
NR 666.100(3)(b)
(b) Gas recovered from hazardous or solid waste landfills when such gas is burned for energy recovery.
NR 666.100(3)(d)
(d) Coke ovens, if the only hazardous waste burned is EPA hazardous waste number K087, decanter tank tar sludge from coking operations.
NR 666.100(4)
(4) Owners and operators of smelting, melting and refining furnaces (including pyrometallurgical devices such as cupolas, sintering machines, roasters and foundry furnaces, but not including cement kilns, aggregate kilns or halogen acid furnaces burning hazardous waste) that process hazardous waste solely for metal recovery are conditionally exempt from regulation under this subchapter, except for ss.
NR 666.101 and
666.112.
NR 666.100(4)(a)
(a) To be exempt from ss.
NR 666.102 to
666.111, an owner or operator of a metal recovery furnace or mercury recovery furnace shall comply with all of the following requirements, except that an owner or operator of a lead or a nickel-chromium recovery furnace, or a metal recovery furnace that burns baghouse bags used to capture metallic dusts emitted by steel manufacturing, shall comply with par.
(c), and owners or operators of lead recovery furnaces that are subject to regulation under the Secondary Lead Smelting national emission standards for hazardous air pollutants (NESHAP) shall comply with sub.
(8).
NR 666.100(4)(a)1.
1. Provide a one-time written notice to the department indicating all of the following:
NR 666.100(4)(a)1.d.
d. The owner or operator will comply with the sampling and analysis and recordkeeping requirements of this subsection.
NR 666.100(4)(a)2.
2. Sample and analyze the hazardous waste and other feedstocks as necessary to comply with this subsection by using appropriate methods.
NR 666.100(4)(a)3.
3. Maintain at the facility for at least 3 years records to document compliance with this subsection including limits on levels of toxic organic constituents and Btu value of the waste, and levels of recoverable metals in the hazardous waste compared to normal nonhazardous waste feedstocks.
NR 666.100(4)(b)
(b) A hazardous waste meeting either of the following criteria is not processed solely for metal recovery:
NR 666.100(4)(b)1.
1. The hazardous waste has a total concentration of organic compounds listed in ch.
NR 661 Appendix VIII, exceeding 500 ppm by weight, as-fired, and so is considered to be burned for destruction. The concentration of organic compounds in a waste as-generated may be reduced to the 500 ppm limit by bona fide treatment that removes or destroys organic constituents. Blending for dilution to meet the 500 ppm limit is prohibited and documentation that the waste has not been impermissibly diluted shall be retained in the records required by par.
(a)3. NR 666.100(4)(b)2.
2. The hazardous waste has a heating value of 5,000 Btu/lb or more, as-fired, and so is considered to be burned as fuel. The heating value of a waste as-generated may be reduced to below the 5,000 Btu/lb limit by bona fide treatment that removes or destroys organic constituents. Blending for dilution to meet the 5,000 Btu/lb limit is prohibited and documentation that the waste has not been impermissibly diluted shall be retained in the records required by par.
(a) 3. NR 666.100(4)(c)
(c) To be exempt from ss.
NR 666.102 to
666.111, an owner or operator of a lead or nickel-chromium or mercury recovery furnace (except for owners or operators of lead recovery furnaces subject to regulation under the Secondary Lead Smelting national emission standards for hazardous air pollutants (NESHAP)) or a metal recovery furnace that burns baghouse bags used to capture metallic dusts emitted by steel manufacturing, shall provide a one-time written notice to the department identifying each hazardous waste burned and specifying whether the owner or operator claims an exemption for each waste under this paragraph or par.
(a). The owner or operator shall comply with par.
(a) for those wastes claimed to be exempt under par.
(a) and shall comply with the requirements below for those wastes claimed to be exempt under this paragraph.
NR 666.100(4)(c)1.a.
a. A waste listed in ch.
NR 666 Appendix IX shall contain recoverable levels of lead, a waste listed in ch.
NR 666 Appendix XII shall contain recoverable levels of nickel or chromium, a waste listed in ch.
NR 666 Appendix XIII shall contain recoverable levels of mercury and contain less than 500 ppm of ch.
NR 661 Appendix VIII organic constituents, and baghouse bags used to capture metallic dusts emitted by steel manufacturing shall contain recoverable levels of metal.
NR 666.100(4)(c)1.d.
d. The owner or operator certifies in the one-time notice that hazardous waste is burned under this paragraph and that sampling and analysis will be conducted or other information will be obtained as necessary to ensure continued compliance with these requirements. Sampling and analysis shall be conducted according to par.
(a) 2. and records to document compliance with this paragraph shall be kept for at least 3 years.
NR 666.100(4)(c)2.
2. The department may decide on a case-by-case basis that the toxic organic constituents in a material listed in ch.
NR 666 Appendix XI, ch.
NR 666 Appendix XII, or ch.
NR 666 Appendix XIII that contains a total concentration of more than 500 ppm toxic organic compounds listed in ch.
NR 661 Appendix VIII may pose a hazard to human health and the environment when burned in a metal recovery furnace exempt from this subchapter. In that situation, after adequate notice and opportunity for comment, the metal recovery furnace shall become subject to this subchapter when burning that material. In making the hazard determination, the department will consider all of the following factors:
NR 666.100(4)(c)2.b.
b. The level of destruction of toxic organic constituents provided by the furnace.
NR 666.100(4)(c)2.c.
c. Whether the acceptable ambient levels established in ch.
NR 666 Appendix IV or ch.
NR 666 Appendix V may be exceeded for any toxic organic compound that may be emitted based on dispersion modeling to predict the maximum annual average off-site ground level concentration.
NR 666.100(6)
(6) The management standards for residues under s.
NR 666.112 apply to any boiler or industrial furnace burning hazardous waste.
NR 666.100(7)
(7) Owners and operators of smelting, melting and refining furnaces (including pyrometallurgical devices such as cupolas, sintering machines, roasters and foundry furnaces) that process hazardous waste for recovery of economically significant amounts of the precious metals gold, silver, platinum, palladium, iridium, osmium, rhodium or ruthenium, or any combination of these are conditionally exempt from regulation under this subchapter, except for s.
NR 666.112. To be exempt from ss.
NR 666.101 to
666.111, an owner or operator shall do all of the following:
NR 666.100(7)(a)
(a) Provide a one-time written notice to the department indicating all of the following:
NR 666.100(7)(a)2.
2. The hazardous waste is burned for legitimate recovery of precious metal.
