NR 661.0032(4)(b)4.c.
c. The calculations performed to determine annual total mass loadings for each K181 constituent in the nonwastewaters during the year.
NR 661.0032(4)(c)
(c)
Determination for generated quantities greater than 1,000 metric tons a year for wastes that contain K181 constituents.
If the total annual quantity of dyes or pigment nonwastewaters generated is greater than 1,000 metric tons, the generator shall perform all of the following steps in order to make a determination that its waste is not K181:
NR 661.0032(4)(c)1.
1. Determine which K181 constituents listed in sub
. (3) are reasonably expected to be present in the wastes based on knowledge of the wastes, such as based on prior sampling and analysis data or information about raw materials used, production processes used, and reaction and degradation products formed.
NR 661.0032(4)(c)2.
2. If 1,2-phenylenediamine is present in the wastes, the generator can use either knowledge or sampling and analysis procedures to determine the level of this constituent in the wastes. For determinations based on use of knowledge, the generator shall comply with the procedures for using knowledge described in par.
(b) and keep the records described in par.
(b) 4. For determinations based on sampling and analysis, the generator shall comply with all of the sampling and analysis and recordkeeping requirements in subds.
3. to
11. NR 661.0032(4)(c)3.
3. Develop a waste sampling and analysis plan or modify an existing plan to collect and analyze representative waste samples for the K181 constituents reasonably expected to be present in the wastes. At a minimum, the plan shall include all of the following:
NR 661.0032(4)(c)3.c.
c. A discussion of how the sampling plan accounts for potential temporal and spatial variability of the wastes.
NR 661.0032(4)(c)3.d.
d. A detailed description of the test methods to be used, including sample preparation, clean up, if necessary, and determinative methods.
NR 661.0032(4)(c)4.
4. Collect and analyze samples in accordance with the waste sampling and analysis plan.
NR 661.0032(4)(c)4.a.
a. The sampling and analysis shall be unbiased, precise, and representative of the wastes.
NR 661.0032(4)(c)4.b.
b. The analytical measurements shall be sufficiently sensitive, accurate and precise to support any claim that the constituent mass loadings are below the listing levels of sub.
(3).
NR 661.0032(4)(c)6.
6. Record the waste quantity represented by the sampling and analysis results.
NR 661.0032(4)(c)7.
7. Calculate constituent-specific mass loadings, product of concentrations and waste quantity.
NR 661.0032(4)(c)8.
8. Keep a running total of the K181 constituent mass loadings over the course of the calendar year.
NR 661.0032(4)(c)9.
9. Determine whether the mass of any of the K181 constituents listed in sub.
(3) generated between January 1 and December 31 of any year is below the K181 listing levels.
NR 661.0032(4)(c)10.
10. Keep all of the following records on site for the 3 most recent calendar years in which the hazardous waste determinations are made:
NR 661.0032(4)(c)10.b.
b. The sampling and analysis results, including quality assurance/quality control data.
NR 661.0032(4)(c)11.
11. Nonhazardous waste determinations shall be conducted annually to verify that the wastes remain nonhazardous.
NR 661.0032(4)(c)11.a.
a. The annual testing requirements are suspended after 3 consecutive successful annual demonstrations that the wastes are nonhazardous. The generator can then use knowledge of the wastes to support subsequent annual determinations.
NR 661.0032(4)(c)11.b.
b. The annual testing requirements are reinstated if the manufacturing or waste treatment processes generating the wastes are significantly altered, resulting in an increase of the potential for the wastes to exceed the listing levels.
NR 661.0032(4)(c)11.c.
c. If the annual testing requirements are suspended, the generator shall keep records of the process knowledge information used to support a nonhazardous determination. If testing is reinstated, a description of the process change shall be retained.
NR 661.0032(4)(d)
(d)
Recordkeeping for the landfill disposal and combustion exemptions. For the purposes of meeting the landfill disposal and combustion condition set out in the K181 listing description, the generator shall maintain on site for 3 years documentation demonstrating that each shipment of waste was received by a landfill unit that is subject to or meets the landfill design standards set out in the listing description, or was treated in combustion units as specified in the listing description.
NR 661.0032(4)(e)
(e)
Waste holding and handling. During the interim period, from the point of generation to completion of the hazardous waste determination, the generator is responsible for storing the wastes appropriately. If the wastes are determined to be hazardous and the generator has not complied with the hazardous waste requirements during the interim period, the generator may be subject to an enforcement action for improper management.
NR 661.0032 History
History: CR 19-082: cr.
Register August 2020 No. 776, eff. 9-1-20; renum. (2) (a) to (2) under s.
13.92 (4) (b) 1., Stats., and correction in (1) (Table) under s.
35.17, Stats.,
Register August 2020 No. 776.
NR 661.0033
NR 661.0033 Discarded commercial chemical products, off-specification species, container residues, and spill residues thereof. All of the following materials or items are hazardous wastes if and when they are discarded or intended to be discarded as described in s.
NR 661.0002 (1) (b) 1., when they are mixed with waste oil or used oil or other material and applied to the land for dust suppression or road treatment, when they are otherwise applied to the land in lieu of their original intended use or when they are contained in products that are applied to the land in lieu of their original intended use, or when, in lieu of their original intended use, they are produced for use as, or as a component of, a fuel, distributed for use as a fuel, or burned as a fuel.
NR 661.0033(1)
(1) Any commercial chemical product, or manufacturing chemical intermediate having the generic name listed in sub.
(5) or
(6).
NR 661.0033(2)
(2) Any off-specification commercial chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in sub.
(5) or
(6).
NR 661.0033(3)
(3) Any residue remaining in a container or in an inner liner removed from a container that has held any commercial chemical product or manufacturing chemical intermediate having the generic name listed in sub.
(5) or
(6), unless the container is empty as defined in s.
NR 661.0007 (2) or
666.507.
NR 661.0033 Note
Note: Unless the residue is being beneficially used or reused, or legitimately recycled or reclaimed; or being accumulated, stored, transported or treated prior to such use, re-use, recycling or reclamation, the department considers the residue to be intended for discard, and thus, a hazardous waste. An example of a legitimate re-use of the residue would be where the residue remains in the container and the container is used to hold the same commercial chemical product or manufacturing chemical intermediate it previously held. An example of the discard of the residue would be where the drum is sent to a drum reconditioner who reconditions the drum but discards the residue.
NR 661.0033(4)
(4) Any residue or contaminated soil, water or other debris resulting from the cleanup of a spill into or on any land or water of any commercial chemical product or manufacturing chemical intermediate having the generic name listed in sub.
(5) or
(6), or any residue or contaminated soil, water or other debris resulting from the cleanup of a spill, into or on any land or water, of any off-specification chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in sub.
(5) or
(6).
NR 661.0033 Note
Note: The phrase “commercial chemical product or manufacturing chemical intermediate having the generic name listed in...” refers to a chemical substance which is manufactured or formulated for commercial or manufacturing use which consists of the commercially pure grade of the chemical, any technical grades of the chemical that are produced or marketed, and all formulations in which the chemical is the sole active ingredient. It does not refer to a material, such as a manufacturing process waste, that contains any of the substances listed in sub. (5) or (6). Where a manufacturing process waste is deemed to be a hazardous waste because it contains a substance listed in sub. (5) or (6), such waste will be listed in either s.
NR 661.0031 or
661.0032 or will be identified as a hazardous waste by the characteristics set forth in subch. C.
NR 661.0033(5)
(5) The commercial chemical products, manufacturing chemical intermediates or off-specification commercial chemical products or manufacturing chemical intermediates referred to in subs.
(1) to
(4) are identified as acute hazardous wastes (H).
NR 661.0033 Note
Note: For convenience, the primary hazardous properties of these materials have been indicated by the letters `T' for toxicity, and `R' for reactivity. Absence of a letter indicates that the compound only is listed for acute toxicity. Wastes are first listed in alphabetical order by substance and then listed again in numerical order by EPA hazardous waste number.
These wastes and their corresponding EPA hazardous waste numbers are:
-
See PDF for table 
1CAS Number given for parent compound only.
NR 661.0033(6)
(6) The commercial chemical products, manufacturing chemical intermediates, or off-specification commercial chemical products referred to in subs.
(1) to
(4) are identified as toxic wastes (T) unless otherwise designated.
NR 661.0033 Note
Note: For convenience, the primary hazardous properties of these materials have been indicated by the letters `T' for toxicity, `R' for reactivity, `I' for ignitability and `C' for corrosivity. Absence of a letter indicates that the compound is only listed for toxicity. Wastes are first listed in alphabetical order by substance and then listed again in numerical order by EPA hazardous waste number.
These wastes and their corresponding EPA hazardous waste numbers are:
-
See PDF for table
1CAS Number given for parent compound only.
NR 661.0033 History
History: CR 19-082: cr.
Register August 2020 No. 776, eff. 9-1-20; correction in (3), (5), (6) made under s.
35.17, Stats.,
Register August 2020 No. 776.
NR 661.0035
NR 661.0035 Deletion of certain hazardous waste codes following equipment cleaning and replacement. NR 661.0035(1)(1)
Wastes from wood preserving processes at plants that do not resume or initiate use of chlorophenolic preservatives will not meet the listing definition of F032 once the generator has met all of the requirements under subs
. (2) and
(3). These wastes may, however, continue to meet another hazardous waste listing description or may exhibit one or more of the hazardous waste characteristics.
NR 661.0035(2)
(2) A generator shall either clean or replace all process equipment that may have come into contact with chlorophenolic formulations or constituents thereof, including treatment cylinders, sumps, tanks, piping systems, drip pads, fork lifts, and trams, in a manner that minimizes or eliminates the escape of hazardous waste or constituents, leachate, contaminated drippage, or hazardous waste decomposition products to the ground water, surface water, or atmosphere.
NR 661.0035(2)(a)1.
1. Prepare and follow an equipment cleaning plan and clean equipment in accordance with par.
(b).
NR 661.0035(2)(a)2.
2. Prepare and follow an equipment replacement plan and replace equipment in accordance with par.
(c).
NR 661.0035(2)(a)3.
3. Document cleaning and replacement in accordance with par.
(c), carried out after termination of use of chlorophenolic preservations.
NR 661.0035(2)(b)2.b.
b. Rinse process equipment with an appropriate solvent until dioxins and dibenzofurans are not detected in the final solvent rinse.
NR 661.0035(2)(b)3.b.
b. “Not detected” means at or below the following lower method calibration limits or MCLs: The 2,3,7,8-TCDD-based MCL—0.01 parts per trillion or ppt, sample weight of 1000 g, IS spiking level of 1 ppt, final extraction volume of 10-50
mL. For other congeners—multiply the values by 1 for TCDF/PeCDD/PeCDF, by 2.5 for HxCDD/HxCDF/HpCDD/HpCDF, and by 5 for OCDD/OCDF.
NR 661.0035(2)(d)1.1. A generator acting under par.
(a) 3. shall document that previous equipment cleaning or replacement was performed in accordance with this section and occurred after cessation of use of chlorophenolic preservatives.
NR 661.0035(3)
(3) The generator shall maintain all of the following records documenting the cleaning and replacement as part of the facility's operating record:
NR 661.0035(3)(b)
(b) Formulations previously used and the date on which their use ceased in each process at the plant.
NR 661.0035(3)(e)
(e) The name and address of any persons who conducted the cleaning and replacement.
NR 661.0035(3)(h)
(h) A description of the sample handling and preparation techniques, including techniques used for extraction, containerization, preservation, and chain-of-custody of the samples.
NR 661.0035(3)(i)
(i) A description of the tests performed, the date the tests were performed, and the results of the tests.
NR 661.0035(3)(j)
(j) The name and model numbers of the instrument used in performing the tests.
NR 661.0035(3)(L)
(L) The following statement signed by the generator or the generator's authorized representative: “I certify under penalty of law that all process equipment required to be cleaned or replaced under s.
NR 661.0035 was cleaned or replaced as represented in the equipment cleaning and replacement plan and accompanying documentation. I am aware that there are significant penalties for providing false information, including the possibility of fine or imprisonment.”
NR 661.0035 History
History: CR 19-082: cr.
Register August 2020 No. 776, eff. 9-1-20.; correction in (2) (b) 4. made under s.
35.17, Stats.,
Register August 2020 No. 776.
