NR 464.02(26)(b)
(b) For purposes of complying with mass emission limits in this chapter, megagram of ODP shall be measured to represent the amount of pulp entering and processed by the equipment system under the specified mass limit.
NR 464.02(26)(c)
(c) For equipment that does not process pulp, megagram of ODP shall be measured to represent the amount of pulp that was processed to produce the gas and liquid streams.
NR 464.02(27)
(27) “Oxygen delignification system" means the equipment that uses oxygen to remove lignin from pulp after high-density stock storage and prior to the bleaching system. The oxygen delignification system equipment includes the blow tank, washers, filtrate tanks, any interstage pulp storage tanks and any other equipment serving the same function as those previously listed.
NR 464.02(28)
(28) “Primary fuel" means the fuel that provides the principal heat input to the combustion device. To be considered primary, the fuel must be able to sustain operation of the combustion device without the addition of other fuels.
NR 464.02(29)
(29) “Process wastewater treatment system" means a collection of equipment, a process or a specific technique that removes or destroys the HAPs in a process wastewater stream. Examples include, but are not limited to, a steam stripping unit, wastewater thermal oxidizer or biological treatment unit.
NR 464.02(30)
(30) “Pulp washing system" means all equipment used to wash pulp and separate spent cooking chemicals following the digester system and prior to the bleaching system, oxygen delignification system or paper machine system at unbleached mills. The pulp washing system equipment includes vacuum drum washers, diffusion washers, rotary pressure washers, horizontal belt filters, intermediate stock chests and their associated vacuum pumps, filtrate tanks, foam breakers or tanks, and any other equipment serving the same function as those previously listed. The pulp washing system does not include deckers, screens, knotters, stock chests or pulp storage tanks following the last stage of pulp washing.
NR 464.02(31)
(31) “Pulping line" means a group of equipment arranged in series such that the wood chips are digested and the resulting pulp progresses through a sequence of steps that may include knotting, refining, washing, thickening, blending, storing, oxygen delignification and any other equipment serving the same function as those previously listed.
NR 464.02(32)
(32) “Pulping process condensates" means any HAP-containing liquid that results from contact of water with organic compounds in the pulping process. Examples of process condensates include digester system condensates, turpentine recovery system condensates, evaporator system condensates, LVHC system condensates, HVLC system condensates and any other condensates from equipment serving the same function as those previously listed. Liquid streams that are intended for byproduct recovery are not considered process condensate streams.
NR 464.02(33)
(33) “Pulping system" means all process equipment, beginning with the digester system, and up to and including the last piece of pulp conditioning equipment prior to the bleaching system, including treatment with ozone, oxygen or peroxide before the first application of a chemical bleaching agent intended to brighten pulp. The pulping system includes pulping process condensates and can include multiple pulping lines.
NR 464.02(34)
(34) “Recovery furnace" means an enclosed combustion device where concentrated spent liquor is burned to recover sodium and sulfur, produce steam and dispose of unwanted dissolved wood components in the liquor.
NR 464.02(35)
(35) “Screen system" means equipment in which oversized particles are removed from the pulp slurry prior to the bleaching or papermaking system washed stock storage.
NR 464.02(36)
(36) “Secondary fiber pulping" means a pulping process that converts a fibrous material, that has previously undergone a manufacturing process, into pulp stock through the addition of water and mechanical energy. The mill then uses that pulp as the raw material in another manufactured product. These mills may also utilize chemical, heat and mechanical processes to remove ink particles from the fiber stock.
NR 464.02(37)
(37) “Semi-chemical pulping" means a pulping process that combines both chemical and mechanical pulping processes. The semi-chemical pulping process produces intermediate yields ranging from 55 to 90%.
NR 464.02(38)
(38) “Soda pulping" means a chemical pulping process that uses sodium hydroxide as the active chemical in the cooking liquor.
NR 464.02(39)
(39) “Spent liquor" means process liquid generated from the separation of cooking liquor from pulp by the pulp washing system containing dissolved organic wood materials and residual cooking compounds.
NR 464.02(40)
(40) “Steam stripper system" means a column, including associated stripper feed tanks, condensers or heat exchangers, used to remove compounds from wastewater or condensates using steam. The steam stripper system also contains all equipment associated with a methanol rectification process including rectifiers, condensers, decanters, storage tanks and any other equipment serving the same function as those previously listed.
NR 464.02(41)
(41) “Strong liquor storage tanks" means all storage tanks containing liquor that has been concentrated in preparation for combustion or oxidation in the recovery process.
NR 464.02(42)
(42) “Sulfite pulping" means a chemical pulping process that uses a mixture of sulfurous acid and bisulfite ion as the cooking liquor.
NR 464.02(43)
(43) “Temperature monitoring device" means a piece of equipment used to monitor temperature and having an accuracy of
+1.0% of the temperature being monitored expressed in degrees Celsius or
+0.5 degrees Celsius (
°C), whichever is greater.
NR 464.02(44)
(44) “Thermal oxidizer" means an enclosed device that destroys organic compounds by thermal oxidation.
NR 464.02(45)
(45) “Turpentine recovery system" means all equipment associated with recovering turpentine from digester system gases including condensers, decanters, storage tanks and any other equipment serving the same function as those previously listed. The turpentine recovery system includes any liquid streams associated with the turpentine recovery process such as turpentine decanter underflow. Liquid streams that are intended for byproduct recovery are not considered turpentine recovery system condensate streams.
NR 464.02(46)
(46) “Weak liquor storage tank" means any storage tank except washer filtrate tanks containing spent liquor recovered from the pulping process and prior to the evaporator system.
NR 464.02 History
History: CR 00-175: cr.
Register March 2002 No. 555, eff. 4-1-02.
NR 464.03
NR 464.03
Standards for the pulping system at kraft, soda and semi-chemical processes. NR 464.03(1)
(1) The owner or operator of each pulping system using the kraft process subject to the requirements of this chapter shall control the total HAP emissions from the following equipment systems, as specified in
subs. (3) and
(4):
NR 464.03(1)(a)
(a) At existing affected sources, the total HAP emissions from the following equipment systems shall be controlled:
NR 464.03(1)(a)2.
2. Each knotter or screen system with a total HAP mass emission rate greater than or equal to the rate specified in
subd. 2. a. or
b. or the combined rate specified in
subd. 2. c.:
NR 464.03(1)(a)2.a.
a. Each knotter system with emissions of 0.05 kilograms or more of total HAP per megagram of ODP (0.1 pounds per ton).
NR 464.03(1)(a)2.b.
b. Each screen system with emissions of 0.10 kilograms or more of total HAP per megagram of ODP (0.2 pounds per ton).
NR 464.03(1)(a)2.c.
c. Each knotter and screen system with emissions of 0.15 kilograms or more of total HAP per megagram of ODP (0.3 pounds per ton).
NR 464.03(1)(a)4.a.
a. Uses any process water other than fresh water or paper machine white water.
NR 464.03(1)(a)4.b.
b. Uses any process water with a total HAP concentration greater than 400 parts per million by weight.
NR 464.03(1)(b)
(b) At new affected sources, the total HAP emissions from the equipment systems listed in
par. (a) 1.,
3. and
5. and all of the following equipment systems shall be controlled:
NR 464.03(2)
(2) The owner or operator of each pulping system using a semi-chemical or soda process subject to the requirements of this chapter shall control the total HAP emissions from the following equipment systems, as specified in
subs. (3) and
(4).
NR 464.03(2)(a)
(a) At each existing affected sources, the total HAP emissions from each LVHC system shall be controlled.
NR 464.03(2)(b)
(b) At each new affected source, the total HAP emissions from each LVHC system and each pulp washing system shall be controlled.
NR 464.03(3)
(3) Equipment systems listed in
subs. (1) and
(2) shall be enclosed and vented into a closed-vent system and routed to a control device that meets the requirements specified in
sub. (4). The enclosures and closed-vent system shall meet the requirements specified in
s. NR 464.08.
NR 464.03(4)
(4) The control device used to reduce total HAP emissions from each equipment system listed in
subs. (1) and
(2) shall do one of the following:
NR 464.03(4)(b)
(b) Reduce the total HAP concentration at the outlet of the thermal oxidizer to 20 parts per million or less by volume, corrected to 10% oxygen on a dry basis.
NR 464.03(4)(c)1.
1. A thermal oxidizer designed and operated at a minimum temperature of 871
°C (1600
°F) and a minimum residence time of 0.75 seconds.
NR 464.03(4)(c)2.
2. A boiler, lime kiln or recovery furnace by introducing the HAP emission stream with the primary fuel or into the flame zone.
NR 464.03(4)(c)3.
3. A boiler or recovery furnace with a heat input capacity greater than or equal to 44 megawatts (150 million British thermal units per hour) by introducing the HAP emission stream with the combustion air.
NR 464.03(5)
(5) Periods of excess emissions reported under
s. NR 464.11 are not a violation of
subs. (3) and
(4) provided that the time of excess emissions, excluding periods of startup, shutdown or malfunction, divided by the total process operating time in a semi-annual reporting period does not exceed any of the following levels:
NR 464.03(5)(a)
(a) One percent for control devices used to reduce the total HAP emissions from the LVHC system.
NR 464.03(5)(b)
(b) Four percent for control devices used to reduce the total HAP emissions from the HVLC system.
NR 464.03(5)(c)
(c) Four percent for control devices used to reduce the total HAP emissions from both the LVHC and HVLC systems.
NR 464.03 History
History: CR 00-175: cr.
Register March 2002 No. 555, eff. 4-1-02.
NR 464.04
NR 464.04
Standards for the pulping system at sulfite processes. NR 464.04(1)(1) The owner or operator of each sulfite process subject to the requirements of this chapter shall control the total HAP emissions from the following equipment systems as specified in
subs. (2) and
(3):
NR 464.04(1)(a)
(a) At existing sulfite affected sources, the total HAP emissions from all of the following equipment systems shall be controlled:
NR 464.04(1)(b)
(b) At new affected sources, the total HAP emissions from the equipment systems listed in
par. (a) and all of the following equipment shall be controlled:
NR 464.04(2)
(2) Equipment listed in
sub. (1) shall be enclosed and vented into a closed-vent system which routes emissions to a control device that meets the requirements specified in
sub. (3). The enclosures and closed-vent system shall meet the requirements specified in
s. NR 464.08. Emissions from equipment listed in
sub. (1) that do not need to be reduced to meet
sub. (3) are not required to be routed to a control device.
NR 464.04(3)
(3) The total HAP emissions from both the equipment systems listed in
sub. (1) and the vents, wastewater and condensate streams from the control device used to reduce HAP emissions shall be controlled as follows:
NR 464.04(3)(a)
(a) Each calcium-based or sodium-based sulfite pulping process shall do one of the following:
NR 464.04(3)(a)1.
1. Emit no more than 0.44 kilograms of total HAP or methanol per megagram (0.89 pounds per ton) of ODP.
NR 464.04(3)(b)
(b) Each magnesium-based or ammonium-based sulfite pulping process shall do one of the following:
NR 464.04(3)(b)1.
1. Emit no more than 1.1 kilograms of total HAP or methanol per megagram (2.2 pounds per ton) of ODP.
NR 464.04 History
History: CR 00-175: cr.
Register March 2002 No. 555, eff. 4-1-02.
NR 464.05
NR 464.05
Standards for the bleaching system. NR 464.05(1)(1) Each bleaching system that does not use any chlorine or chlorinated compounds for bleaching is exempt from the requirements of this section. Owners or operators of the following bleaching systems shall meet all the provisions of this section:
NR 464.05(1)(b)
(b) Bleaching systems bleaching pulp from kraft, sulfite or soda pulping processes that use any chlorinated compounds.
NR 464.05(1)(c)
(c) Bleaching systems bleaching pulp from mechanical pulping processes using wood, or from any process using secondary or non-wood fibers, that use chlorine dioxide.
NR 464.05(2)
(2) The equipment at each bleaching stage of the bleaching systems listed in
sub. (1) where chlorinated compounds are introduced shall be enclosed and vented into a closed-vent system which routes emissions to a control device that meets the requirements specified in
sub. (3). The enclosures and closed-vent system shall meet the requirements specified in
s. NR 464.08. If process modifications are used to achieve compliance with the emission limits specified in
sub. (3) (b) or
(c), enclosures and closed-vent systems are not required.
NR 464.05(3)
(3) The control device used to reduce chlorinated HAP emissions, not including chloroform, from the equipment specified in
sub. (2) shall do one of the following:
NR 464.05(3)(a)
(a) Reduce the total chlorinated HAP mass in the vent stream entering the control device by 99% or more by weight.
NR 464.05(3)(b)
(b) Achieve a treatment device outlet concentration of 10 parts per million or less by volume of total chlorinated HAP.
NR 464.05(3)(c)
(c) Achieve a treatment device outlet mass emission rate of 0.001 kg of total chlorinated HAP mass per megagram (0.002 pounds per ton) of ODP.
NR 464.05(4)
(4) The owner or operator of each bleaching system subject to
sub. (1) (b) shall comply with
par. (a) or
(b) to reduce chloroform air emissions to the atmosphere, except the owner or operator of each bleaching system complying with extended compliance under
s. NR 464.01 (1) (e) 1. to
3. shall comply with
par. (a). The owner or operator shall:
