NR 463.06(3)(a)(a) Except as provided in pars. (b) and (c), an owner or operator of an affected source subject to the requirements of this subchapter is required to conduct an initial performance test as required under s. NR 460.06, using the procedures and test methods listed in ss. NR 460.06 (2) and (5) and 463.09. NR 463.06(3)(b)(b) If the owner or operator of an affected source meets all of the following criteria, an initial performance test is not required to be conducted under this subchapter: NR 463.06(3)(b)1.1. The affected source is a hard chromium electroplating tank, a decorative chromium electroplating tank or a chromium anodizing tank. NR 463.06(3)(b)2.2. A wetting agent is used in the plating or anodizing bath to inhibit chromium emissions from the affected source. NR 463.06(3)(c)(c) If the affected source is a decorative chromium electroplating tank using a trivalent chromium bath, and the owner or operator is subject to the provisions of s. NR 463.04 (5), an initial performance test is not required to be conducted under this subchapter. NR 463.06 HistoryHistory: Cr. Register, September, 1997, No. 501, eff. 10-1-97; CR 05-039: am. (1) (c), (e), (3) (b) 1. and 3. Register February 2006 No. 602, eff. 3-1-06; CR 04-023: am. (2) (a), (3) (a), (b) (intro.) and (c) Register December 2008 No, 636, eff. 1-1-09. NR 463.07NR 463.07 Monitoring to demonstrate continuous compliance. The owner or operator of an affected source subject to the emission limitations of this subchapter shall conduct monitoring according to the type of air pollution control technique that is used to comply with the emission limitation. The monitoring required to demonstrate continuous compliance with the emission limitations is identified in this section for the air pollution control techniques expected to be used by the owners or operators of affected sources. NR 463.07(1)(a)(a) During the initial performance test, the owner or operator of an affected source, or a group of affected sources under common control, complying with the emission limitations in s. NR 463.04 through the use of a composite mesh-pad system shall determine the outlet chromium concentration using the test methods and procedures in s. NR 463.09 (3), and shall establish as a site-specific operating parameter the pressure drop across the system, setting the value that corresponds to compliance with the applicable emission limitation, using the procedures in s. NR 463.09 (4) (e). An owner or operator may conduct multiple performance tests to establish a range of compliant pressure drop values, or may set as the compliant value the average pressure drop measured over the 3 test runs of one performance test and accept ± 2 inches of water column from this value as the compliant range. NR 463.07(1)(b)(b) On and after the date on which the initial performance test is required to be completed under s. NR 460.06, the owner or operator of an affected source, or group of affected sources under common control, shall monitor and record the pressure drop across the composite mesh-pad system once each day that any affected source is operating. To be in compliance with the standards in s. NR 463.04, the composite mesh-pad system shall be operated within ± 2 inches of water column of the pressure drop value established during the initial performance test, or shall be operated within the range of compliant values for pressure drop established during multiple performance tests. NR 463.07(1)(c)(c) The owner or operator of an affected source complying with the emission limitation of s. NR 463.04 through the use of a composite mesh-pad system may repeat the performance test and establish as a new site-specific operating parameter the pressure drop across the composite mesh-pad system according to the requirements in par. (a) or (b). To establish a new site-specific operating parameter for pressure drop, the owner or operator shall satisfy all of the following requirements: NR 463.07(1)(d)(d) The requirement to operate a composite mesh-pad system within the range of pressure drop values established under pars. (a) to (c) does not apply during the automatic-washdown cycles of the composite-mesh pad system. NR 463.07(2)(a)(a) During the initial performance test, the owner or operator of an affected source, or group of affected sources under common control, complying with the emission limitations in s. NR 463.04 through the use of a packed-bed scrubber system shall determine the outlet chromium concentration using the procedures in s. NR 463.09 (3), and shall establish as site-specific operating parameters the pressure drop across the system and the velocity pressure at the common inlet of the control device, setting the value that corresponds to compliance with the applicable emission limitation using the procedures in s. NR 463.09 (4) (d) and (e). An owner or operator may conduct multiple performance tests to establish a range of compliant operating parameter values. Alternatively, the owner or operator may set as the compliant value the average pressure drop and inlet velocity pressure measured over the 3 test runs of one performance test, and accept ± 1 inch of water column from the pressure drop value and ± 10% from the velocity pressure value as the compliant range. NR 463.07(2)(b)(b) On and after the date on which the initial performance test is required to be completed under s. NR 460.06, the owner or operator of an affected source, or group of affected sources under common control, shall monitor and record the velocity pressure at the inlet to the packed-bed scrubber and the pressure drop across the scrubber system once each day that any affected source is operating. To be in compliance with the standards in s. NR 463.04, the scrubber system shall be operated within ±10% of the velocity pressure value established during the initial performance test, and within ±1 inch of water column of the pressure drop value established during the initial performance test, or within the range of compliant operating parameter values established during multiple performance tests. NR 463.07(3)(3) Packed-bed scrubber/composite mesh-pad system. The owner or operator of an affected source, or group of affected sources under common control, that uses a packed-bed scrubber in conjunction with a composite mesh-pad system to meet the emission limitations of s. NR 463.04 shall comply with the monitoring requirements for composite mesh-pad systems as identified in sub. (1). NR 463.07(4)(a)(a) During the initial performance test, the owner or operator of an affected source, or group of affected sources under common control, complying with the emission limitations in s. NR 463.04 through the use of a fiber-bed mist eliminator shall determine the outlet chromium concentration using the procedures in s. NR 463.09 (3), and shall establish as a site-specific operating parameter the pressure drop across the fiber-bed mist eliminator and the pressure drop across the control device installed upstream of the fiber bed to prevent plugging, setting the value that corresponds to compliance with the applicable emission limitation using the procedures in s. NR 463.09 (4) (e). An owner or operator may conduct multiple performance tests to establish a range of compliant pressure drop values, or may set as the compliant value the average pressure drop measured over the 3 test runs of one performance test and accept ±1 inch of water column from this value as the compliant range. NR 463.07(4)(b)(b) On and after the date on which the initial performance test is required to be completed under s. NR 460.06, the owner or operator of an affected source, or group of affected sources under common control, shall monitor and record the pressure drop across the fiber-bed mist eliminator, and the control device installed upstream of the fiber bed to prevent plugging, once each day that any affected source is operating. To be in compliance with the standards in s. NR 463.04, the fiber-bed mist eliminator and the upstream control device shall be operated within ±1 inch of water column of the pressure drop value established during the initial performance test, or shall be operated within the range of compliant values for pressure drop established during multiple performance tests. NR 463.07(5)(5) Wetting agent-type or combination wetting agent-type/foam blanket fume suppressants. NR 463.07(5)(a)(a) During the initial performance test, the owner or operator of an affected source complying with the emission limitations in s. NR 463.04 through the use of a wetting agent in the electroplating or anodizing bath shall determine the outlet chromium concentration using the procedures in s. NR 463.09 (3). The owner or operator shall establish as the site-specific operating parameter the surface tension of the bath using Method 306B in Appendix A of 40 CFR part 63, incorporated by reference in s. NR 484.04 (25), setting the maximum value that corresponds to compliance with the applicable emission limitation. In lieu of establishing the maximum surface tension during the performance test, the owner or operator may accept 45 dynes/cm (3.1 x 10-3 pound-force per foot (lbf /ft)) as measured by a stalagmometer or 35 dynes/cm (2.4 x 10-3 lbf /ft) as measured by a tensiometer as the maximum surface tension value that corresponds to compliance with the applicable emission limitation. However, the owner or operator is exempt from conducting a performance test only if the criteria of s. NR 463.06 (3) (b) are met. NR 463.07(5)(b)(b) On and after the date on which the initial performance test is required to be completed under s. NR 460.06, the owner or operator of an affected source shall monitor the surface tension of the electroplating or anodizing bath. Operation of the affected source at a surface tension greater than the value established during the performance test or greater than 45 dynes/cm (3.1 x 10-3 lbf /ft) as measured by a stalagmometer or 35 dynes/cm (2.4 x 10-3 lbf /ft) as measured by a tensiometer if the owner or operator is using this value in accordance with par. (a), shall constitute noncompliance with the standards in s. NR 463.04. The surface tension shall be monitored according to the following schedule: NR 463.07(5)(b)1.1. The surface tension shall be measured once every 4 hours during operation of the tank with a stalagmometer or a tensiometer as specified in Method 306B in Appendix A of 40 CFR part 63, incorporated by reference in s. NR 484.04. NR 463.07(5)(b)2.2. The time between monitoring may be increased if there have been no exceedances. The surface tension shall be measured once every 4 hours of tank operation for the first 40 hours of tank operation after the compliance date. Once there are no exceedances during 40 hours of tank operation, surface tension measurement may be conducted once every 8 hours of tank operation. Once there are no exceedances during 40 more hours of tank operation, surface tension measurement may be conducted once every 40 hours of tank operation on an ongoing basis, until an exceedance occurs. The minimum frequency of monitoring allowed by this subchapter is once every 40 hours of tank operation. NR 463.07(5)(b)3.3. Once an exceedance occurs as indicated through surface tension monitoring, the original monitoring schedule of once every 4 hours shall be resumed. A subsequent decrease in frequency shall follow the schedule laid out in subd. 2. For example, if an owner or operator had been monitoring an affected source once every 40 hours and an exceedance occurs, subsequent monitoring would take place once every 4 hours of tank operation. Once an exceedance does not occur for 40 hours of tank operation, monitoring may occur once every 8 hours of tank operation. Once an exceedance does not occur for 40 hours of tank operation on this schedule, monitoring may occur once every 40 hours of tank operation. NR 463.07(5)(c)(c) Once a bath solution is drained from the affected tank and a new solution added, the original monitoring schedule of once every 4 hours shall be resumed, with a decrease in monitoring frequency allowed following the procedures of par. (b) 2. and 3. NR 463.07(6)(a)(a) During the initial performance test, the owner or operator of an affected source complying with the emission limitations in s. NR 463.04 through the use of a foam blanket in the electroplating or anodizing bath shall determine the outlet chromium concentration using the procedures in s. NR 463.09 (3), and shall establish as the site-specific operating parameter the thickness of the foam blanket, setting the minimum thickness that corresponds to compliance with the applicable emission limitation. In lieu of establishing the minimum foam blanket thickness during the performance test, the owner or operator may accept 2.54 centimeters (1 inch) as the minimum foam blanket thickness that corresponds to compliance with the applicable emission limitation. All foam blanket measurements shall be taken in close proximity to the workpiece or cathode area in the plating tank. NR 463.07(6)(b)(b) On and after the date on which the initial performance test is required to be completed under s. NR 460.06, the owner or operator of an affected source shall monitor the foam blanket thickness of the electroplating or anodizing bath. Operation of the affected source at a foam blanket thickness less than the value established during the performance test, or less than 2.54 cm (1 inch) if the owner or operator is using this value in accordance with par. (a), constitutes noncompliance with the standards in s. NR 463.04. The foam blanket thickness shall be measured according to the following schedule: NR 463.07(6)(b)1.1. The foam blanket thickness shall be measured once every hour of tank operation. NR 463.07(6)(b)2.2. The time between monitoring may be increased if there have been no exceedances. The foam blanket thickness shall be measured once every hour of tank operation for the first 40 hours of tank operation after the compliance date. Once there are no exceedances for 40 hours of tank operation, foam blanket thickness measurement may be conducted once every 4 hours of tank operation. Once there are no exceedances during 40 more hours of tank operation, foam blanket thickness measurement may be conducted once every 8 hours of tank operation on an ongoing basis, until an exceedance occurs. The minimum frequency of monitoring allowed by this subchapter is once per 8 hours of tank operation. NR 463.07(6)(b)3.3. Once an exceedance occurs as indicated through foam blanket thickness monitoring, the original monitoring schedule of once every hour shall be resumed. A subsequent decrease in frequency shall follow the schedule laid out in subd. 2. For example, if an owner or operator had been monitoring an affected source once every 8 hours and an exceedance occurs, subsequent monitoring would take place once every hour of tank operation. Once an exceedance does not occur for 40 hours of tank operation, monitoring may occur once every 4 hours of tank operation. Once an exceedance does not occur for 40 hours of tank operation on this schedule, monitoring may occur once every 8 hours of tank operation. NR 463.07(6)(c)(c) Once a bath solution is drained from the affected tank and a new solution added, the original monitoring schedule of once every hour shall be resumed, with a decrease in monitoring frequency allowed following the procedures of par. (b) 2. and 3. NR 463.07(7)(a)(a) If the owner or operator of an affected source uses both a fume suppressant and add-on control device and both are needed to comply with the applicable emission limit, monitoring requirements as identified in subs. (1) to (6), and the work practice standards of Table 1 of this subchapter, apply for each of the control techniques used. NR 463.07(7)(b)(b) If the owner or operator of an affected source uses both a fume suppressant and add-on control device, but only one of these techniques is needed to comply with the applicable emission limit, monitoring requirements as identified in subs. (1) to (6), and work practice standards of Table 1 of this subchapter, apply only for the control technique used to achieve compliance. NR 463.07(8)(b)(b) After receipt and consideration of an application for an alternative monitoring method, the department may approve alternatives to any monitoring methods or procedures of this subchapter including, but not limited to, the following: NR 463.07(8)(b)1.1. Alternative monitoring requirements when installation or use of monitoring devices specified in this subchapter would not provide accurate measurements due to interferences caused by substances within the effluent gases. NR 463.07(8)(b)2.2. Alternative locations for installing monitoring devices when the owner or operator can demonstrate that installation at alternate locations will enable accurate and representative measurements. NR 463.07 HistoryHistory: Cr. Register, September, 1997, No. 501, eff. 10-1-97; CR 05-039: am. (1) (a), (b), (5) (a), (b) (intro.) and (7) (b), cr. (1) (c) and (d) Register February 2006 No. 602, eff. 3-1-06; CR 04-023: am. (intro.), (5) (b) 2., (6) (b) 2., (7) (a), (8) (b) (intro.) and 1. Register December 2008 No. 636, eff. 1-1-09. NR 463.08NR 463.08 Alternative control devices. An owner or operator who uses an air pollution control device not listed in s. NR 463.07 shall submit a description of the device, test results collected in accordance with s. NR 463.09 (3) verifying the performance of the device for reducing chromium emissions to the atmosphere to the level required by this subchapter, a copy of the operation and maintenance plan referenced in s. NR 463.05 including proposed work practice standards, and appropriate operating parameters that will be monitored to establish continuous compliance with the standards in s. NR 463.04. The monitoring plan submitted identifying the continuous compliance monitoring is subject to the department’s approval. NR 463.09NR 463.09 Performance test requirements and test methods. NR 463.09(1)(1) Performance test requirements. Performance tests shall be conducted using the test methods and procedures in this section and s. NR 460.06. The test plan to be followed shall be made available to the department prior to the testing, if requested. Performance test results shall be documented in complete test reports that contain all of the following information: NR 463.09(1)(c)(c) A description of sampling and analytical procedures and any modifications to standard procedures. NR 463.09(1)(f)(f) Records of operating conditions during the test, preparation of calibration standards, and calibration procedures. NR 463.09(1)(g)(g) Raw data sheets for field sampling and field and laboratory analyses. NR 463.09(2)(2) Use of operation permit performance test results for compliance demonstration. NR 463.09(2)(a)(a) If the owner or operator of an affected source conducts performance testing at startup to obtain an operation permit under ch. NR 407, the results of the testing may be used to demonstrate compliance with this subchapter if all of the following conditions are met: NR 463.09(2)(a)1.1. The test methods and procedures identified in sub. (3) were used during the performance test. NR 463.09(2)(a)2.2. The performance test was conducted under representative operating conditions for the source. NR 463.09(2)(a)4.4. The owner or operator of the affected source for which the performance test was conducted has sufficient data to establish the operating parameter values that correspond to compliance with the standards in s. NR 463.04, as required for continuous compliance monitoring under s. NR 463.07. NR 463.09(2)(b)(b) The results of tests conducted prior to December 1991 in which Method 306A in Appendix A of 40 CFR part 63, incorporated by reference in s. NR 484.04, was used to demonstrate the performance of a control technique are not acceptable. NR 463.09(3)(3) Test methods. Each owner or operator subject to the provisions of this subchapter and required by s. NR 463.06 (3) to conduct an initial performance test shall use the test methods identified in this section to demonstrate compliance with the standards in s. NR 463.04. NR 463.09(3)(a)(a) Method 306 or Method 306A in Appendix A of 40 CFR part 63, both titled “Determination of Chromium Emissions From Decorative and Hard Chromium Electroplating and Anodizing Operations,” which are incorporated by reference in s. NR 484.04, shall be used to determine the chromium concentration from hard or decorative chromium electroplating tanks or chromium anodizing tanks. The sampling time and sample volume for each run of Methods 306 and 306A shall be at least 120 minutes and 1.70 dscm (60 dscf), respectively. Methods 306 and 306A allow the measurement of either total chromium or hexavalent chromium emissions. For the purposes of this subchapter, sources using chromic acid baths may demonstrate compliance with the emission limits of s. NR 463.04 by measuring either total chromium or hexavalent chromium. The hexavalent chromium concentration measured by these methods is equal to the total chromium concentration for the affected operations. NR 463.09(3)(b)(b) Method 306B in Appendix A of 40 CFR part 63, “Surface Tension Measurement and Recordkeeping for Tanks Used at Decorative Chromium Electroplating and Anodizing Facilities,” incorporated by reference in s. NR 484.04, shall be used to measure the surface tension of electroplating and anodizing baths. NR 463.09(3)(c)(c) Alternate test methods may also be used if the method has been validated using Method 301 in Appendix A of 40 CFR part 63, incorporated by reference in s. NR 484.04, and if approved by the department. Procedures for requesting and obtaining approval are contained in s. NR 460.06 (5). NR 463.09(4)(4) Establishing site-specific operating parameter values. NR 463.09(4)(a)(a) Each owner or operator required to establish site-specific operating parameters shall follow the procedures in this subsection. NR 463.09(4)(b)(b) All monitoring equipment shall be installed such that representative measurements of emissions or process parameters from the affected source are obtained. For monitoring equipment purchased from a vendor, verification of the operational status of the monitoring equipment shall include execution of the manufacturer’s written specifications or recommendations for installation, operation and calibration of the system. NR 463.09(4)(b)1.1. Specifications for differential pressure measurement devices used to measure velocity pressure shall be in accordance with section 2.2 of Method 2 in Appendix A of 40 CFR part 60, incorporated by reference in s. NR 484.04. NR 463.09(4)(b)2.2. Specifications for differential pressure measurement devices used to measure pressure drop across a control system shall be in accordance with manufacturer’s accuracy specifications. NR 463.09(4)(c)(c) The surface tension of electroplating and anodizing baths shall be measured using Method 306B in Appendix A of 40 CFR part 63, “Surface Tension Measurement and Recordkeeping for Tanks Used at Decorative Chromium Electroplating and Anodizing Facilities,” incorporated by reference in s. NR 484.04. This method shall also be followed when wetting agent type or combination wetting agent/foam blanket type fume suppressants are used to control chromium emissions from a hard chromium electroplating tank and surface tension measurement is conducted to demonstrate continuous compliance. NR 463.09(4)(d)(d) The owner or operator of a source required to measure the velocity pressure at the inlet to an add-on air pollution control device in accordance with s. NR 463.07 (2), shall establish the site-specific velocity pressure as follows: NR 463.09(4)(d)1.1. Locate a velocity traverse port in a section of straight duct that connects the hooding on the plating tank or tanks with the control device. The port shall be located as close to the control system as possible, and shall be placed a minimum of 2 duct diameters downstream and 0.5 diameter upstream of any flow disturbance such as a bend, expansion or contraction (see Method 1 in Appendix A of 40 CFR part 60, incorporated by reference in s. NR 484.04). If 2.5 diameters of straight duct work does not exist, locate the port 0.8 of the distance between flow disturbances downstream and 0.2 of the distance between flow disturbances upstream from the respective flow disturbances. NR 463.09(4)(d)2.2. A 12-point velocity traverse of the duct to the control device shall be conducted along a single axis according to Method 2 in Appendix A of 40 CFR part 60, incorporated by reference in s. NR 484.04, using an S-type pitot tube; measurement of the barometric pressure and duct temperature at each traverse point is not required, but is suggested. Mark the S-type pitot tube as specified in Method 1 in Appendix A of 40 CFR part 60, incorporated by reference in s. NR 484.04, with 12 points. Measure the velocity pressure (∆p) values for the velocity points and record. Determine the square root of the individual velocity point ∆p values and average. The point with the square root value that comes closest to the average square root value is the point of average velocity. The ∆p value measured for this point during the performance test shall be used as the reference for future monitoring. NR 463.09(4)(e)(e) The owner or operator of a source required to measure the pressure drop across the add-on air pollution control device in accordance with s. NR 463.07 (1) to (4) may establish the pressure drop in accordance with the following guidelines: NR 463.09(4)(e)1.1. Pressure taps shall be installed at any of the following locations: NR 463.09(4)(e)1.a.a. At the inlet and outlet of the control system. In this case the inlet tap would be installed in the ductwork just prior to the control device and the corresponding outlet pressure tap would be installed on the outlet side of the control device prior to the blower or on the downstream side of the blower. NR 463.09(4)(e)1.b.b. On each side of the packed bed within the control system or on each side of each mesh pad within the control system. NR 463.09(4)(e)1.c.c. On the front side of the first mesh pad and back side of the last mesh pad within the control system. NR 463.09(4)(e)2.a.a. As free from pluggage as possible and away from any flow disturbances such as cyclonic demisters. NR 463.09(4)(e)2.b.b. Situated such that no air infiltration at the measurement site will occur that could bias the measurement.
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Chs. NR 400-499; Environmental Protection – Air Pollution Control
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