NR 422.143(7)(d)1.c.c. Calculate the VOC composite partial pressure of the solvent by using the formula for “VOC composite partial pressure.” For the purpose of this calculation, the blended solvent shall be assumed to be an ideal solution where “Raoult’s Law” applies. The partial vapor pressures of each compound at 68°F shall be used in the formula. The VOC composite partial pressure shall be calculated as follows: where:
Wi is the weight of the “i”th VOC compound, in grams.
Ww is the weight of water, in grams.
We is the weight of exempt compound, in grams.
MWi is the molecular weight of the “i”th VOC compound, in grams per gram-mole.
MWw is the molecular weight of water, in grams per gram-mole.
MWe is the molecular weight of the “e”th exempt compound, in grams per gram-mole.
PPc is the VOC composite vapor pressure at 68°F, in mm Hg.
VPi is the vapor pressure of the “i”th VOC compound at 68°F, in mm Hg.
NR 422.143(7)(d)2.2. If not diluted prior to use, the owner or operator shall use formulation information provided by the supplier, such as a safety data sheet (SDS) or equivalent information from the supplier, as long as it is based on results determined in accordance with the procedure in subd. 1. NR 422.143(8)(8) Compliance schedule and certification requirements. NR 422.143(8)(am)(am) The owner or operator of a heatset web lithographic printing press that is installed after July 1, 2019, shall perform a compliance emission test within 180 days after installation of the press and shall submit to the department no later than 60 days after the test written certification that the press is in compliance with the applicable requirements of sub. (3) and a demonstration of compliance in accordance with subs. (6), (7), and (8). NR 422.143(8)(bm)(bm) The owner or operator of any lithographic printing press, other than a heatset web press, that is installed after July 1, 2019, shall submit to the department, no later than 180 days after installation of the press, written certification that the press is in compliance with the applicable requirements of sub. (3) and a demonstration of compliance in accordance with subs. (6), (7), and (8). NR 422.143(8)(c)(c) Facilities subject to this section and located in an area described under sub. (1) (a) 2. c., shall comply with the applicable requirements of this section by the following deadlines: NR 422.143(8)(c)1.1. Facilities that were initially constructed in an area described in sub. (1) (a) 2. c., prior to the effective date of its designation as moderate, serious, severe, or extreme ozone nonattainment, shall comply with applicable requirements within 180 days of the effective date of designation. NR 422.143(8)(c)2.2. Facilities that were initially constructed in an area described in sub. (1) (a) 2. c., after the area has been designated as moderate, serious, severe, or extreme ozone nonattainment, shall comply with applicable requirements upon startup. NR 422.143 HistoryHistory: CR 08-102: cr. Register July 2009 No. 643, eff. 8-1-09; CR 11-005: renum. (3) (c) to be (3) (c) (intro.) and am., cr. (3) (c) 1., 2., am. (6) (d) Register January 2012 No. 673, eff. 2-1-12; CR 18-067: am. (1) (a), cr. (1) (a) 1., 2., (am), am. (1m) (f), (2) (intro.), (a), (3) (c) (intro.) and 2. cons. and renum. to (3) (c) and am., (5) (a) renum. to (5), am. (5) (title), cr. (5) (b), am. (6) (intro.), (a), cr. (6) (a) 4., am. (6) (d), (e), (7) (a), (b) 1., 2., (7) (c) (renum.) to (7) (c) (intro.) and am., cr. (7) (c) 1., 2., (d), (8) (b) 1. renum. to (8) (am) and am., (8) (b) 2. renum. to (8) (bm) and am., cr. (8) (c) Register June 2019 No. 762, eff. 7-1-19; correction in numbering of (1) (a) made under s. 13.92 (4) (b) 1., and corrections in (1) (a) (intro.), 1., (am), (7) (d) 1. c., 2. made under s. 35.17, Stats., Register June 2019 No. 762; correction in (1) (am) made under s. 13.92 (4) (b) 7., Stats., Register June 2019. NR 422.144(1)(a)(a) This section applies to the owner or operator of a printing facility that operates a letterpress printing press in the county of Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington, or Waukesha if actual VOC emissions from all letterpress printing presses, including related letterpress cleaning activities at the facility, before consideration of controls, equal or exceed 3 tons on a 12 consecutive month rolling basis. When determining the VOC emissions for applicability under this paragraph, the VOC emissions from the cleaning of electronic components of a letterpress printing press, pre-press and post-press cleaning operations and the use of janitorial supplies used to clean around a letterpress printing press are excluded. The VOC emissions from solvents used in cold cleaners are excluded for applicability purposes. NR 422.144 NoteNote: Janitorial supplies are cleaners, such as detergent-based products, used to clean the floor or for other general cleaning purposes, for example, areas not contaminated with spilled ink.
NR 422.144(1)(b)(b) To determine VOC emissions under par. (a), the VOC content of a letterpress ink shall be multiplied by 0.8 for a heatset ink, or multiplied by 0.05 for a non-heatset ink, to account for VOC retention on the substrate. NR 422.144(2)(2) Retention factors and capture efficiencies. For purposes of determining VOC emissions from letterpress printing operations, the following retention factors and capture efficiencies may be used: NR 422.144(2)(a)(a) A 20% VOC retention factor for heatset petroleum oil inks printed on absorptive substrates, meaning 80% of the VOC in the ink is emitted during the printing process and is available for capture and control by an add-on pollution control device. NR 422.144(2)(b)(b) A 95% VOC retention factor for sheet-fed and non-heatset web petroleum oil inks printed on absorptive substrates, meaning 5% of the VOC in the ink is emitted during the printing process. NR 422.144(2)(c)(c) A 50% VOC retention factor for cleaning solution in shop towels where the composite partial vapor pressure of the VOC in the cleaning solution is less than 10 mm of Hg at 20°C (68°F) and the cleaning solution and contaminated shop towels are kept in closed containers, meaning 50% of the VOC used on the shop towels is emitted during the cleaning process. NR 422.144(2)(d)(d) A 100% VOC capture efficiency for inks. All the VOC in the ink that is not retained is assumed to be volatilized in the press dryer. Capture efficiency testing for heatset dryers is not required if it is demonstrated that pressure in the dryer is negative relative to the surrounding press room and the airflow is into the dryer. NR 422.144(2)(e)(e) A 40% VOC capture efficiency for automatic blanket or roller wash where the VOC composite partial vapor pressure of the blanket or roller wash is less than 10 mm of Hg at 20°C (68°F). NR 422.144(3)(3) Exemptions. The following exemptions apply to letterpress printing operations in Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington and Waukesha counties: NR 422.144(3)(a)(a) Up to 110 gallons of blanket or roller wash, on a 12-consecutive month rolling basis, which do not meet the low VOC composite partial vapor pressure or low VOC content requirements as stated in this section, are exempt from the requirements of this section. NR 422.144(3)(b)(b) The printing of books on a heatset letterpress press is exempt from the requirements of sub. (4) (a). NR 422.144(3)(c)(c) Heatset letterpress presses with a maximum web width of up to 22 inches are exempt from the requirements of sub. (4) (a). NR 422.144(4)(a)1.1. Beginning on March 1, 2013, no owner or operator of a heatset web letterpress printing press may operate, or cause, allow or permit the operation of a letterpress press that has maximum theoretical emissions of VOCs, from the dryer, equal to or greater than 25 tons per year from heatset inks, unless the owner or operator installs and operates an emission control device and meets the applicable emission limitation as follows: NR 422.144(4)(a)1.a.a. If the emission control device was first installed prior to February 1, 2012, the owner or operator shall reduce VOC emissions from the letterpress press dryer exhaust by 90% by weight as carbon, minus methane and ethane, or maintain a maximum dryer exhaust outlet VOC concentration of 120 ppmv, as carbon, minus methane and ethane. NR 422.144(4)(a)1.b.b. If the emission control device was first installed after February 1, 2012, the owner or operator shall reduce VOC emissions from the letterpress press dryer exhaust by 95% by weight as carbon, minus methane and ethane, or maintain a maximum dryer exhaust outlet VOC concentration of 120 ppmv, as carbon, minus methane and ethane. NR 422.144(4)(a)2.2. The first installation date for a control device for purposes of subd. 1. is the date the device was first ever installed. The first installation date does not change if the device is later moved to a new location. NR 422.144(4)(a)3.3. If a combined dryer and control device is a part of the press design, a 100% capture at the control inlet may be assumed for purposes of meeting the emission reduction limits in subd. 1. NR 422.144(4)(b)(b) Blanket or roller wash. Except as provided in sub. (3) (a), on and after May 1, 2012, no owner or operator of a letterpress printing press may use, or cause, allow or permit the use of a blanket or roller wash with a VOC composite vapor pressure of greater than or equal to 10 mm of Hg at 68°F or greater than or equal to 70% by weight. NR 422.144(5)(a)(a) Beginning on February 1, 2012, the owner or operator of a letterpress press subject to this subsection shall store all solvents, solvent solutions and any shop towels or other applicator moistened with solvents or solvent solutions that are used in cleaning operations related to letterpress printing in covered non-absorbent, non-leaking containers, except when filling or emptying the container. NR 422.144(6)(6) Recordkeeping requirements. In addition to the applicable recordkeeping requirements in s. NR 439.04, the owner or operator of any letterpress printing press shall collect and record the applicable information specified in this subsection. The information shall be maintained at the facility for a minimum of 5 years and shall be made available to a department representative at any time during normal working hours. The information required is: NR 422.144(6)(a)(a) For a heatset web letterpress printing press using a control device, for each day of operation: NR 422.144(6)(a)2.2. A log of the operating time for the control device, control device monitoring equipment, and the associated printing line or operation. NR 422.144(6)(a)3.3. A maintenance log for the control device and control device monitoring equipment detailing all routine and non-routine maintenance performed and including the dates and duration of any outages. NR 422.144(6)(b)(b) For each blanket or roller wash batch, monthly records of the percent by weight VOC content or the composite partial vapor pressure, as applied, and the date and time the batch was prepared. NR 422.144(6)(c)(c) For each month of operation, the volume of all blanket or roller wash used which does not meet either of the emission limitations in sub. (4) (b). NR 422.144(7)(a)(a) The owner or operator of a heatset web letterpress printing press shall demonstrate compliance with the appropriate destruction efficiency or emission rate in sub. (4) (a) by performing compliance emission tests on each control device. The initial emission tests shall be performed by the compliance deadline in sub. (8) (a) 1. or (b) 1. or 2. Each emission test shall follow the methods and procedures listed in s. NR 439.07. Method 25 or 25A in 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (19) and (20), shall be used to determine the VOC concentration at the sampling points, including the exhaust stream entering and existing the control device. When determining the VOC concentration, the probe shall be heated during testing to at least the exhaust gas stream temperature. In cases where the anticipated outlet VOC concentration of the control device is less than 50 ppmv as carbon, Method 25A shall be used. NR 422.144(7)(b)(b) The owner or operator of a heatset web letterpress printing press shall perform the compliance emission tests required under par. (a) according to one of the following applicable test schedules: NR 422.144(7)(b)1.1. Any facility with allowable VOC emissions from letterpress printing presses of 100 tons or more per year shall perform an emission test which demonstrates compliance with sub. (4) (a) every 24 months. Each biennial test shall be performed within 90 days of the anniversary date of the initial emission test. NR 422.144(7)(b)2.2. Any facility with allowable VOC emissions from letterpress printing presses of less than 100 tons per year shall perform an emission test which demonstrates compliance with sub. (4) (a) every 48 months. Each test shall be performed within 90 days of the anniversary date of the initial emission test. NR 422.144(7)(c)(c) The VOC content of heatset web, sheet-fed and cold set web letterpress inks and blanket or roller wash shall be determined by Method 24 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 484.04 (13). NR 422.144(8)(8) Compliance schedule and certification requirements. NR 422.144(8)(a)1.1. The owner or operator of a letterpress printing press shall comply with the applicable emission limitations for the dryer exhaust in sub. (4) (a) by February 1, 2013. NR 422.144(8)(a)2.2. The owner or operator of a heatset web letterpress printing press shall submit to the department, no later than July 1, 2012, written certification that the press is in compliance with the applicable requirements of subs. (4) and (5) and shall provide a demonstration of compliance in accordance with subs. (6) and (7). A compliance emission test performed in accordance with s. NR 439.07 no more than 2 years prior to the compliance deadline, which demonstrates compliance with sub. (4) (a), is acceptable as a demonstration of compliance in accordance with sub. (7). NR 422.144(8)(b)1.1. The owner or operator of a heatset web letterpress printing press which is installed after May 1, 2012 shall perform a compliance emission test within 180 days after installation of the press and shall submit to the department no later than 60 days after the test written certification that the press is in compliance with the applicable requirements of subs. (4) and (5) and a demonstration of compliance in accordance with subs. (6) and (7). NR 422.144(8)(b)2.2. The owner or operator of any letterpress printing press, other than a heatset web press, which is installed after May 1, 2012 shall submit to the department, no later than 180 days after installation of the press, written certification that the press is in compliance with the applicable requirements of subs. (4) and (5) and a demonstration of compliance in accordance with subs. (6) and (7). NR 422.144 HistoryHistory: CR 11-005: cr. Register January 2012 No. 673, eff. 2-1-12. NR 422.145(1)(a)(a) Subsections (2), (3), and (4) apply to all screen printing units at screen printing facilities that are either of the following: NR 422.145(1)(a)1.1. Located in the county of Kenosha, Milwaukee, Ozaukee, Racine, Washington, or Waukesha and which have maximum theoretical emissions of VOCs from all screen printing units at the facility equal to or greater than 25 tons per year. NR 422.145(1)(a)2.2. Located in the county of Kewaunee, Manitowoc, or Sheboygan and which have maximum theoretical emissions of VOCs from all screen printing units at the facility equal to or greater than 100 tons per year. NR 422.145(1)(b)(b) Except as provided in sub. (1m), subs. (2m), and (4) apply to the owner or operator of a screen printing facility located in the county of Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington, or Waukesha if VOC emissions from all industrial cleaning operations, before consideration of controls, equal or exceed 3 tons per year on a 12 consecutive month basis. NR 422.145(1m)(1m) Exemptions. The following exemptions are applicable to various provisions of this section: NR 422.145(1m)(b)(b) Subsection (2m) (a) does not apply to cleaning conducted in conjunction with performance laboratory testing on coatings or inks; research and development programs; and laboratory tests in quality assurance laboratories. NR 422.145(1m)(c)(c) Subsection (2m) (a) and (e) do not apply to cleaning with aerosol products if 160 fluid ounces or less of VOC-containing aerosol products are used per day for industrial cleaning operations, per facility. NR 422.145(1m)(f)(f) Subsection (2m) (e) does not apply to the cleaning of the nozzle tips of automated spray equipment systems, except for robotic systems that are programmed to spray into a closed container. NR 422.145(2)(a)(a) General. No owner or operator of a screen printing unit may cause, allow or permit the emission of any VOCs in excess of 0.40 kilograms per liter (3.3 pounds per gallon) of ink or coating, excluding water, delivered to an applicator, except as provided in pars. (b) and (c). NR 422.145(2)(b)(b) Special purpose inks and coatings. No owner or operator of a screen printing unit using a special purpose ink or coating may cause, allow or permit the emission of any VOCs in excess of 0.80 kilograms per liter (6.7 pounds per gallon) of special purpose ink or coating, excluding water, delivered to an applicator. NR 422.145(2)(c)(c) Roll coating. No owner or operator of a screen printing unit may cause, allow or permit the emission of any VOCs in excess of 0.80 kilograms per liter (6.7 pounds per gallon), excluding water, delivered to a roll coating applicator associated with screen printing. NR 422.145(2m)(a)(a) Solvent and solvent solution requirements. Except as provided under par. (d), no owner or operator of a facility may cause, allow or permit the use of a solvent or solvent solution for industrial cleaning operations unless the VOC content of the solvent or solvent solution is less than or equal to the applicable VOC content listed in Table 5 for the respective cleaning operation. For the purposes of this subsection, VOC content shall be defined as in s. NR 423.02 (11r). NR 422.145(2m)(b)(b) Cleaning devices and methods requirements. Except as provided under par. (d), the owner or operator of a facility shall comply with the following requirements associated with the identified cleaning devices or methods when using solvents or solvent solutions: NR 422.145(2m)(b)1.1. Physically rub a surface with a porous applicator such as a rag, paper, sponge, or a cotton swab moistened with solvent or solvent solution. NR 422.145(2m)(b)2.2. Closed containers or hand held spray bottles from which solvents or solvent solutions are applied without a propellant-induced force. NR 422.145(2m)(b)3.3. Cleaning equipment which has a solvent or solvent solution container that is closed during cleaning operations, except when depositing and removing objects to be cleaned, and is closed during non-operation with the exception of maintenance and repair to the cleaning equipment itself.
