Arsenic 1.000
Cadmium 0.850
Chromium (III) 0.860
Chromium (VI) 0.962
Copper 0.960
Lead 0.792
Mercury 0.85
Nickel 0.997
Selenium 0.922
Zinc 0.986
NR 105.06(8)(b)(b) The translation of the WQCD into the water quality criterion which accounts for site-specific conditions (WQCTRAN) shall be performed as follows: WQCTRAN = (Translator)(WQCD)
Where: Translator (unitless) = ((MP)(TSS) + MD)/MD
MP = Particle-bound concentration of the pollutant (ug/g) in receiving water.
MD = Dissolved concentration of the pollutant in receiving water (ug/L).
TSS = Total Suspended Solids (g/L) concentration in receiving water.
NR 105.06(8)(c)(c) The procedures in pars. (a) and (b) may also be used for the conversion of secondary values from total recoverable to dissolved. NR 105.06 NoteNote: * - Criterion listed is applicable to the “total recoverable” form except for chlorine which is applicable to the “total residual” form.
NR 105.06 NoteNote: This table is reserved for criteria that USEPA has indicated may be available in the near future.
NR 105.06 NoteNote: *Criterion listed is applicable to the “total recoverable” form except for chlorine which is applicable to the “total residual” form.
NR 105.06 HistoryHistory: Cr. Register, February, 1989, No. 398, eff. 3-1-89; am. (5) (f) and Tables 2, 2a, 4, 4a and 6, Register, July, 1995, No. 475, eff. 8-1-95; am. (1) (a) 1., 2., 4., and 5., (1) (b), (3) (intro.), (a) to (g), (4) (a) 1., 7. to 13., (5) (c), renum. (1) (a) 6. to be (1) (a) 10., (3) (h) to be (3) (i) and am. (1) (a) 10, (4) (a) 6. to be (4) (a) 6. a., (4) (b) to be (4) (c), (5) (e) to (i) to be (5) (d) to (h) and am. (5) (e) to (g), cr. (3) (h), (4) (a) 6. b., (4) (b), (5) (b) 3., (6) to (8), r. and recr., Tables 1 to 2a, 3 to 6, r. (5) (d); am. Tables 1 and 5, Register, January, 2000, No. 529, eff. 2-1-00; CR 03-050: am. Tables 2 and 6, cr. Tables 2C and 4B Register February 2004 No. 578, eff. 3-1-04; CR 07-110: am Tables 2, 2A, 5 and 6 Register November 2008 No. 635, eff. 12-1-08; CR 09-123: am. (5) (h), (8) (a), Tables 4B and 5 Register July 2010 No. 655, eff. 8-1-10. NR 105.07(1)(1) The wildlife criterion is the concentration of a substance which if not exceeded protects Wisconsin’s wildlife from adverse effects resulting from ingestion of surface waters of the state and from ingestion of aquatic organisms taken from surface waters of the state. NR 105.07(1)(a)(a) For any substance not shown in Table 7, the wildlife criterion (WC) is the lower of the available mammalian or avian wildlife values (WVs) calculated pursuant to sub. (2). A wildlife criterion protective of Wisconsin’s reptile fauna may be calculated pursuant to sub. (2) whenever data specific to reptiles are available. NR 105.07(1)(b)(b) Table 7 contains the wildlife criteria calculated according to the procedures of this chapter. NR 105.07(2)(a)(a) Mammalian and avian wildlife values shall be calculated as follows using information available from scientifically acceptable studies of animal species exposed repeatedly to the substance via oral routes including gavage: WV = NOAEL x WtA x SSF
W + S[FTLi x BAFTLi]
NR 105.07(2)(b)(b) The selection of the species sensitivity factor (SSF) shall be based on the available toxicological data base and available physicochemical and toxicokinetic properties of the substance and the amount and quality of available data. NR 105.07(2)(c)(c) The bald eagle, kingfisher, herring gull, mink and otter are representative of avian and mammalian species to be protected by wildlife criteria. A NOAEL specific to each taxonomic class is used to calculate WVs for each of the 5 representative species. The avian WV is the geometric mean of the WVs calculated for the 3 representative avian species. The mammalian WV is the geometric mean of the WVs calculated for the 2 representative mammalian species. NR 105.07(2)(d)(d) In those cases in which more than one NOAEL is available, the following shall apply: NR 105.07(2)(d)1.1. If more than one NOAEL is available within a taxonomic class, based on the same endpoint of toxicity, the NOAEL from the most sensitive species shall be used. NR 105.07(2)(d)2.2. If more than one NOAEL is available for a given species, based on the same enpoint of toxicity, the NOAEL for that species shall be calculated using the geometric mean of those NOAELs. NR 105.07(2)(e)(e) Because wildlife consume fish from both trophic levels 3 and 4, baseline BAFs shall be available for both trophic levels 3 and 4 to calculate either a criterion or secondary value for a chemical. When appropriate, ingestion through consumption of invertebrates, plants, mammals and birds in the diet of wildlife species to be protected shall be included. NR 105.07(3)(3) In those cases in which a no observed adverse effect level (NOAEL) is available from studies of mammalian or avian species exposed repeatedly to the substance via oral routes including gavage, but is available in units other than mg/kg-d as specified in sub. (2), the following procedures shall be used to express the NOAEL prior to calculating the wildlife value: NR 105.07(3)(a)(a) If the NOAEL is given in milligrams of toxicant per liter of water consumed (mg/L), the NOAEL shall be multiplied by the daily average volume of water consumed by the test animals in liters per day (L/d) and divided by the average weight of the test animals in kilograms (kg). NR 105.07(3)(b)(b) If the NOAEL is given in milligrams of toxicant per kilogram of food consumed (mg/kg), the NOAEL shall be multiplied by the average amount of food in kilograms consumed daily by the test animals (kg/d) and divided by the average weight of the test animals in kilograms (kg). NR 105.07(4)(4) In those cases in which a NOAEL is unavailable and a lowest observed adverse effect level (LOAEL) is available from studies of animal species exposed repeatedly to the substance via oral routes including gavage, the LOAEL may be substituted with proper adjustment to estimate the NOAEL. An uncertainty factor of between one and 10 may be applied to the LOAEL, depending on the sensitivity of the adverse effect, to reduce the LOAEL into the range of a NOAEL. If the LOAEL is available in units other than mg/kg-d, the LOAEL shall be expressed in the same manner as that specified for the NOAEL in sub. (3). NR 105.07(5)(5) In instances where a NOAEL is based on subchronic data, an uncertainty factor may be applied to extrapolate from subchronic to chronic levels. The value of the uncertainty factor may not be less than 0.1 and may not exceed 1.0. This factor is to be used when assessing highly bioaccumulative substances where toxicokinetic considerations suggest that a bioassay of limited length underestimates chronic effects. NR 105.07(6)(6) If drinking or feeding rates are not available for representative species, drinking (W) and feeding rates (FTLi) shall be calculated for representative mammalian or avian species by using the allometric equations given in pars. (a) and (b). NR 105.07(6)(a)(a) For mammalian species the allometric equations are as follows: NR 105.07(6)(b)(b) For avian species the allometric equations are as follows: NR 105.07 NoteNote: Criteria to protect domestic animals will be considered on an as needed basis using a model that accounts for domestic animal exposure through drinking water. Because domestic animals do not regularly consume aquatic organisms, the wildlife exposure model is not appropriate.
NR 105.07 HistoryHistory: Cr. Register, February, 1989, No. 398, eff. 3-1-89; am. table 7, Register, July, 1991, No. 427, eff. 8-1-91; am. (1), (2) (a), (b), (3) (intro.), (6) (intro.), r. and recr. (2) (c), (5), cr. (2) (d), (e), r. (6) (a), renum. (6) (b) and (c) to be (6) (a) and (b) and am., Register, August, 1997, No. 500, eff. 9-1-97. NR 105.08(1)(1) The human threshold criterion (HTC) is the maximum concentration of a substance established to protect humans from adverse effects resulting from contact with or ingestion of surface waters of the state and from ingestion of aquatic organisms taken from surface waters of the state. Human threshold criteria are derived for those toxic substances for which a threshold dosage or concentration can be estimated below which no adverse effect or response is likely to occur. NR 105.08(2)(2) For noncarcinogenic components of mixtures in effluents, interactions among substances may be additive, antagonistic or synergistic and may be accounted for by a model that is supported by credible scientific evidence. The risks are assumed to be additive when substances are members of the same structural class and cause potential adverse effects via the same mechanism of action, influencing the same kind of endpoint, and shall be accounted for by a model that is supported by credible scientific evidence. NR 105.08(3)(3) Human threshold criteria are listed in Table 8. Criteria for the same substance may be different depending on the surface water classification, due to the lipid value of representative fish, a component of the BAF, and whether or not the water may be a source of drinking water. Further application of these criteria to protect drinking water and downstream uses in the Great Lakes system shall be according to s. NR 106.06 (1) NR 105.08(4)(4) To derive human threshold criteria for substances not included in Table 8 the following methods shall be used: NR 105.08(4)(a)(a) The human threshold criterion shall be calculated as follows: NR 105.08(4)(b)(b) For surface waters classified as public water supplies, if the human threshold criterion for a toxic substance as calculated in par. (a) exceeds the maximum contaminant level (MCL) for that substance as specified in ch. NR 809 or the July 8, 1987 Federal Register (52 FR 25690), the MCL shall be used as the human threshold criterion. NR 105.08(5)(5) The acceptable daily exposure (ADE) referenced in sub. (4) represents the maximum amount of a substance which if ingested daily for a lifetime results in no adverse effects to humans. Paragraphs (a) to (c) list methods for determining the acceptable daily exposure. NR 105.08(5)(a)(a) The department shall review available references for acceptable daily exposure or equivalent values, such as a reference dose (RfD) as used by the U.S. environmental protection agency, and for human or animal toxicological data from which an acceptable daily exposure can be derived. Suitable references for review include, but are not limited to, those presented in s. NR 105.04 (5). NR 105.08(5)(b)(b) When human or animal toxicological data are available, the department may derive an acceptable daily exposure by using as guidance procedures presented by the U.S. environmental protection agency in “Water Quality Criteria Documents; Availability” (45 FR 79318, November 28, 1986). Additional guidance for deriving acceptable daily exposures from toxicological data are given in subds. 1. to 4. Alternate procedures may be used if supported by credible scientific evidence. NR 105.08(5)(b)1.1. No observable adverse effect levels (NOAELs) and lowest observable adverse effect levels (LOAELs) from studies of humans or mammalian test species shall be divided by an uncertainty factor to derive an acceptable daily exposure. Uncertainty factors reflect uncertainties in predicting acceptable exposure levels for the general human population based upon experimental animal data or limited human data. Factors to be considered when selecting an uncertainty factor include, but are not limited to, interspecies and individual variations in response and susceptibility to a toxicant, and the quality and quantity of the available data. The following guidelines shall be considered when selecting an uncertainty factor: NR 105.08(5)(b)1.a.a. Use an uncertainty factor of 10 when extrapolating from valid experimental results from studies on prolonged ingestion by humans. This 10-fold factor protects sensitive members of the human population. NR 105.08(5)(b)1.b.b. Use an uncertainty factor of 100 when extrapolating from valid results of long-term feeding studies on experimental animals with results of studies of human ingestion not available or insufficient (e.g., acute exposure only). This represents an additional 10-fold uncertainty factor in extrapolating data from the average animal to the average human. NR 105.08(5)(b)1.c.c. Use an uncertainty factor of 1000 when extrapolating from less than chronic results on experimental animals with no useful long-term or acute human data. This represents an additional 10-fold uncertainty factor in extrapolating from less than chronic to chronic exposures. NR 105.08(5)(b)1.d.d. Use an additional uncertainty factor of between 1 and 10 depending on the severity of the adverse effect when deriving an acceptable daily exposure from a lowest observable adverse effect level (LOAEL). This uncertainty factor reduces the LOAEL into the range of a no observable adverse effect level (NOAEL). NR 105.08(5)(b)1.e.e. Use an additional uncertainty factor of 10 when deriving an acceptable daily exposure for a substance which the U.S. environmental protection agency classifies as a “group C” carcinogen, but which is not defined as a carcinogen in s. NR 105.03 (13). NR 105.08(5)(b)2.2. Results from studies of humans or mammalian test species used to derive acceptable daily exposures shall have units of milligrams of toxicant per kilogram of body weight per day (mg/kg-d). When converting study results to the required units, a water consumption of 2 liters per day (L/d) and a body weight of 70 kilograms (kg) is assumed for humans. The following examples and procedures illustrate the conversion of units: NR 105.08(5)(b)2.a.a. Results from human studies which are expressed in milligrams of toxicant per liter of water consumed (mg/L) are converted to mg/kg-d by multiplying the results by 2 L/d and dividing by 70 kg. NR 105.08(5)(b)2.b.b. Results from animal studies which are expressed in milligrams of toxicant per liter of water consumed (mg/L) are converted to mg/kg-d by multiplying the results by the daily average volume of water consumed by the test animals in liters per day (L/d) and dividing by the average weight of the test animals in kilograms (kg). NR 105.08(5)(b)2.c.c. Results from animal studies which are expressed in milligrams of toxicant per kilogram of food consumed (mg/kg) are converted to mg/kg-d by multiplying the results by the average amount of food consumed daily by the test animals in kilograms per day (kg/d) and dividing by the average weight of the test animals in kilograms (kg). NR 105.08(5)(b)2.d.d. If a study does not specify water or food consumption rates, or body weight of the test animals, standard values taken from appropriate references, such as the National Institute of Occupational Safety and Health, 1980, Registry of Toxic Effects of Chemical Substances, may be used to convert units. NR 105.08(5)(b)2.e.e. Results from animal studies in which test animals were not exposed to the toxicant each day of the test period shall be multiplied by the ratio of days that the test animals were dosed to the total days of the test period. For the purposes of this adjustment, the test period is defined as the interval beginning with the administration of the first dose and ending with the administration of the last dose, inclusive.
