NR 440.33(1)(b)(b) Any facility under par. (a) that commences construction or modifications after October 16, 1974, is subject to the requirements of this section.
NR 440.33(2)(2)Definitions. As used in this section, terms not defined in this subsection have the meanings given in s. NR 440.02.
NR 440.33(2)(a)(a) “Calcine” means the solid materials produced by a roaster.
NR 440.33(2)(b)(b) “Copper converter” means any vessel to which copper matte is charged and oxidized to copper.
NR 440.33(2)(c)(c) “Dryer” means any facility in which a copper sulfide ore concentrate charge is heated in the presence of air to eliminate a portion of the moisture from the charge, provided less than 5% of the sulfur contained in the charge is eliminated in the facility.
NR 440.33(2)(d)(d) “Fossil fuel” means natural gas, petroleum, coal and any form of solid, liquid or gaseous fuel derived from such materials for the purpose of creating useful heat.
NR 440.33(2)(e)(e) “High level of volatile impurities” means a total smelter charge containing more than 0.2 weight percent arsenic, 0.1 weight percent antimony, 4.5 weight percent lead or 5.5 weight percent zinc, on a dry basis.
NR 440.33(2)(f)(f) “Primary copper smelter” means any installation or any intermediate process engaged in the production of copper from copper sulfide ore concentrates through the use of pyrometallurgical techniques.
NR 440.33(2)(g)(g) “Reverberatory smelting furnace” means any vessel in which the smelting of copper sulfide ore concentrates or calcines is performed and in which the heat necessary for smelting is provided primarily by combustion of fossil fuel.
NR 440.33(2)(h)(h) “Roaster” means any facility in which a copper sulfide ore concentrate charge is heated in the presence of air to eliminate a significant portion (5% or more) of the sulfur contained in the charge.
NR 440.33(2)(i)(i) “Smelting” means processing techniques for the melting of a copper sulfide ore concentrate or calcine charge leading to the formation of separate layers of molten slag, molten copper, or copper matte, or all 3.
NR 440.33(2)(j)(j) “Smelting furnace” means any vessel in which the smelting of copper sulfide ore concentrate or calcines is performed and in which the heat necessary for smelting is provided by an electric current, rapid oxidation of a portion of the sulfur contained in the concentrate as it passes through an oxidizing atmosphere, or the combustion of a fossil fuel.
NR 440.33(2)(k)(k) “Sulfuric acid plant” means any facility producing sulfuric acid by the contact process.
NR 440.33(2)(L)(L) “Total smelter charge” means the weight (dry basis) of all copper sulfide ore concentrates processed at a primary copper smelter, plus the weight of all other solid materials introduced into the roasters and smelting furnaces at a primary copper smelter, except calcine, over a one-month period.
NR 440.33(3)(3)Standard for particulate matter.
NR 440.33(3)(a)(a) On and after the date on which the performance test required to be conducted by s. NR 440.08 is completed, no owner or operator subject to the provisions of this section may cause to be discharged into the atmosphere from any dryer any gases which contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf).
NR 440.33(4)(4)Standard for sulfur dioxide.
NR 440.33(4)(a)(a) On and after the date on which the performance test required to be conducted by s. NR 440.08 is completed, no owner or operator subject to the provisions of this section may cause to be discharged into the atmosphere from any roaster, smelting furnace or copper converter any gases which contain sulfur dioxide in excess of 0.065% by volume, except as provided in pars. (b) and (c).
NR 440.33(4)(b)(b) Reverberatory smelting furnaces are exempt from par. (a) during periods when the total smelter charge at the primary copper smelter contains a high level of volatile impurities.
NR 440.33(4)(c)(c) A change in the fuel combusted in a reverberatory smelting furnace may not be considered a modification under this chapter.
NR 440.33(5)(5)Standard for visible emissions.
NR 440.33(5)(a)(a) On and after the date on which the performance test required to be conducted by s. NR 440.08 is completed, no owner or operator subject to the provisions of this section may cause to be discharged into the atmosphere from any dryer any visible emissions which exhibit greater than 20% opacity.
NR 440.33(5)(b)(b) On and after the date on which the performance test required to be conducted by s. NR 440.08 is completed, no owner or operator subject to the provisions of this section may cause to be discharged into the atmosphere from any affected facility that uses a sulfuric acid plant to comply with the standard set forth in sub. (4), any visible emissions which exhibit greater than 20% opacity.
NR 440.33(6)(6)Monitoring of operations.
NR 440.33(6)(a)(a) The owner or operator of any primary copper smelter subject to sub. (4) (b) shall keep a monthly record of the total smelter charge and the weight percent (dry basis) of arsenic, antimony, lead and zinc contained in this charge. The analytical methods and procedures employed to determine the weight of the total smelter charge and the weight percent of arsenic, antimony, lead and zinc shall be approved by the department and shall be accurate to within ± 10%.
NR 440.33(6)(b)(b) The owner or operator of any primary copper smelter subject to the provisions of this section shall install and operate:
NR 440.33(6)(b)1.1. A continuous monitoring system to monitor and record the opacity of gases discharged into the atmosphere from any dryer. The span of this system shall be set at 80 to 100% opacity.
NR 440.33(6)(b)2.2. A continuous monitoring system to monitor and record sulfur dioxide emissions discharged into the atmosphere from any roaster, smelting furnace or copper converter subject to sub. (4) (a). The span of this system shall be set at a sulfur dioxide concentration of 0.20% by volume.
NR 440.33(6)(b)2.a.a. The continuous monitoring system performance evaluation required under s. NR 440.13 (3) shall be completed prior to the initial performance test required under s. NR 440.08.