K1 is the material balance and conversion factor, 2.982 x 10-4 (Mg-min)/hr-dscm-%) [9.31 x 10-6 (ton-min)/(hr-dscf-%)]
K2 is the material balance and conversion factor, 2.088 x 10-3 (Mg-min)/(hr-dscm-%) [6.52 x 10-5 (ton-min)/(hr-dscf-%)]
K3 is the material balance and conversion factor, 9.94 x 10-5 (Mg-min)/(hr-dscm-%) [3.1 x 10-6 (ton-min)/(hr-dscf-%)]
NR 440.26(7)(b)3.b.b. The emission correction factor, integrated sampling and analysis procedure of Method 3B of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), shall be used to determine CO2, CO and O2 concentrations. NR 440.26(7)(c)(c) If auxiliary liquid or solid fossil fuels are burned in an incinerator-waste heat boiler, the owner or operator shall determine the emission rate of PM permitted in sub. (3) (b) as follows: NR 440.26(7)(c)1.1. The allowable emission rate (Es) of PM shall be computed for each run using the following equation: where:
Es is the emission rate of PM allowed, kg/Mg (lb/ton) of coke burn-off in catalyst regenerator
F is the emission standard, 1.0 kg/Mg (2.0 lb/ton) of coke burn-off in catalyst regenerator
A is the allowable incremental rate of PM emission, 7.5 x 10-4 kg/million J (0.10 lb/million Btu)
H is the heat input rate from solid or liquid fossil fuel, million J/hr (million Btu/hr)
Rc is the coke burn-off rate, Mg coke/hr (ton coke/hr)
NR 440.26(7)(c)2.2. Procedures subject to the approval of the department shall be used to determine the heat input rate. NR 440.26(7)(d)(d) The owner or operator shall determine compliance with the CO standard in sub. (4) (a) by using the integrated sampling technique of Method 10 to determine the CO concentration (dry basis). The sampling time for each run shall be 60 minutes. NR 440.26(7)(e)1.1. The owner or operator shall determine compliance with the H2S standard in sub. (5) (a) 1. as follows: Method 11, 15, 15A or 16 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), shall be used to determine the H2S concentration. The gases entering the sampling train should be at about atmospheric pressure. If the pressure in the refinery fuel gas lines is relatively high, a flow control valve may be used to reduce the pressure. If the line pressure is high enough to operate the sampling train without a vacuum pump, the pump may be eliminated from the sampling train. The sample shall be drawn from a point near the centroid of the fuel gas line. NR 440.26(7)(e)1.a.a. For Method 11, the sampling time and sample volume shall be at least 10 minutes and 0.010 dscm (0.35 dscf). Two samples of equal sampling time shall be taken at about 1-hour intervals. The arithmetic average of these 2 samples shall constitute a run. NR 440.26 NoteNote: For most fuel gas, sampling time exceeding 20 minutes may result in depletion of the collection solution, although fuel gases containing low concentrations of H2S may necessitate sampling for longer periods of time.
NR 440.26(7)(e)1.b.b. For Method 15 or 16, at least 3 injects over a 1-hour period shall constitute a run. NR 440.26(7)(e)2.2. Where emissions are monitored by sub. (6) (a) 3., compliance with sub. (6) (a) 1. shall be determined using Method 6 or 6C and Method 3 or 3A of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1). A 1-hour sample shall constitute a run. Method 6 samples shall be taken at a rate of approximately 2 liters/min. The ppm correction factor (Method 6) and the sampling location in par. (f) 1. apply. Method 4 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), shall be used to determine the moisture content of the gases. The sampling point for Method 4 shall be adjacent to the sampling point for Method 6 or 6C. NR 440.26(7)(f)(f) The owner or operator shall determine compliance with the SO2 and the H2S and reduced sulfur standards in sub. (5) (a) 2. as follows: NR 440.26(7)(f)1.1. Method 6 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), shall be used to determine the SO2 concentration. The concentration in mg/dscm obtained by Method 6 or 6C is multiplied by 0.3754 to obtain the concentration in ppm. The sampling point in the duct shall be the centroid of the cross section if the cross-sectional area is less than 5.00 m2 (53.8 ft2) or at a point no closer to the walls than 1.00 m (39.4 in.) if the cross-sectional area is 5.00 m2 or more and the centroid is more than 1 m from the wall. The sampling time and sample volume shall be at least 10 minutes and 0.010 dscm (0.35 dscf) for each sample. Eight samples of equal sampling times shall be taken at about 30-minute intervals. The arithmetic average of these 8 samples shall constitute a run. For Method 6C, a run shall consist of the arithmetic average of 4 1-hour samples. Method 4 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), shall be used to determine the moisture content of the gases. The sampling point for Method 4 shall be adjacent to the sampling point for Method 6 or 6C. The sampling time for each sample shall be equal to the time it takes for 2 Method 6 samples. The moisture content from this sample shall be used to correct the corresponding Method 6 samples for moisture. For documenting the oxidation efficiency of the control device for reduced sulfur compounds, Method 15 of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1), shall be used following the procedures of subd. 2. NR 440.26(7)(f)2.2. Method 15 shall be used to determine the reduced sulfur and H2S concentrations. Each run shall consist of 16 samples taken over a minimum of 3 hours. The sampling point shall be the same as the described for Method 6 in subd. 1. To ensure minimum residence time for the sample inside the sample lines, the sampling rate shall be at least 3.0 lpm (0.10 cfm). The SO2 equivalent for each run shall be calculated after being corrected for moisture and oxygen as the arithmetic average of the SO2 equivalent for each sample during the run. Method 4 shall be used to determine the moisture content of the gases as in subd. 1. The sampling time for each sample shall be equal to the time it takes for 4 Method 15 samples. NR 440.26(7)(f)3.3. The oxygen concentration used to correct the emission rate for excess air shall be obtained by the integrated sampling and analysis procedure of Method 3 or 3A of 40 CFR part 60, Appendix A, incorporated by reference in s. NR 440.17 (1). The samples shall be taken simultaneously with the SO2 reduced sulfur and H2S, or moisture samples. The SO2, reduced sulfur and H2S samples shall be corrected to zero percent excess air using the equation in par. (h) 6.