NR 422.143(7)(c)(c) The VOC content of the as-applied fountain solutions and cleaning solutions shall be determined by any of the following methods: NR 422.143(7)(c)2.2. If diluted prior to use, a calculation shall be performed for VOC content that combines the method referred in s. NR 439.06 (3) (j) for the concentrated materials used to prepare the as-applied fountain solution or cleaning solution, and the proportions in which they are mixed to make the as-applied fountain solution or cleaning solution. NR 422.143(7)(d)(d) The VOC composite partial vapor pressure of each cleaning solution shall be determined by any of the following methods: NR 422.143(7)(d)1.1. If diluted prior to use, calculate the VOC composite vapor pressure of the as-applied solvent by using the formula for “VOC composite vapor pressure” as follows: NR 422.143(7)(d)1.a.a. Determine the identity and quantity of each compound in a blended organic solvent. NR 422.143(7)(d)1.c.c. Calculate the VOC composite partial pressure of the solvent by using the formula for “VOC composite partial pressure.” For the purpose of this calculation, the blended solvent shall be assumed to be an ideal solution where “Raoult’s Law” applies. The partial vapor pressures of each compound at 68°F shall be used in the formula. The VOC composite partial pressure shall be calculated as follows: where:
Wi is the weight of the “i”th VOC compound, in grams.
Ww is the weight of water, in grams.
We is the weight of exempt compound, in grams.
MWi is the molecular weight of the “i”th VOC compound, in grams per gram-mole.
MWw is the molecular weight of water, in grams per gram-mole.
MWe is the molecular weight of the “e”th exempt compound, in grams per gram-mole.
PPc is the VOC composite vapor pressure at 68°F, in mm Hg.
VPi is the vapor pressure of the “i”th VOC compound at 68°F, in mm Hg.
NR 422.143(7)(d)2.2. If not diluted prior to use, the owner or operator shall use formulation information provided by the supplier, such as a safety data sheet (SDS) or equivalent information from the supplier, as long as it is based on results determined in accordance with the procedure in subd. 1. NR 422.143(8)(8) Compliance schedule and certification requirements. NR 422.143(8)(am)(am) The owner or operator of a heatset web lithographic printing press that is installed after July 1, 2019, shall perform a compliance emission test within 180 days after installation of the press and shall submit to the department no later than 60 days after the test written certification that the press is in compliance with the applicable requirements of sub. (3) and a demonstration of compliance in accordance with subs. (6), (7), and (8). NR 422.143(8)(bm)(bm) The owner or operator of any lithographic printing press, other than a heatset web press, that is installed after July 1, 2019, shall submit to the department, no later than 180 days after installation of the press, written certification that the press is in compliance with the applicable requirements of sub. (3) and a demonstration of compliance in accordance with subs. (6), (7), and (8). NR 422.143(8)(c)(c) Facilities subject to this section and located in an area described under sub. (1) (a) 2. c., shall comply with the applicable requirements of this section by the following deadlines: NR 422.143(8)(c)1.1. Facilities that were initially constructed in an area described in sub. (1) (a) 2. c., prior to the effective date of its designation as moderate, serious, severe, or extreme ozone nonattainment, shall comply with applicable requirements within 180 days of the effective date of designation. NR 422.143(8)(c)2.2. Facilities that were initially constructed in an area described in sub. (1) (a) 2. c., after the area has been designated as moderate, serious, severe, or extreme ozone nonattainment, shall comply with applicable requirements upon startup. NR 422.143 HistoryHistory: CR 08-102: cr. Register July 2009 No. 643, eff. 8-1-09; CR 11-005: renum. (3) (c) to be (3) (c) (intro.) and am., cr. (3) (c) 1., 2., am. (6) (d) Register January 2012 No. 673, eff. 2-1-12; CR 18-067: am. (1) (a), cr. (1) (a) 1., 2., (am), am. (1m) (f), (2) (intro.), (a), (3) (c) (intro.) and 2. cons. and renum. to (3) (c) and am., (5) (a) renum. to (5), am. (5) (title), cr. (5) (b), am. (6) (intro.), (a), cr. (6) (a) 4., am. (6) (d), (e), (7) (a), (b) 1., 2., (7) (c) (renum.) to (7) (c) (intro.) and am., cr. (7) (c) 1., 2., (d), (8) (b) 1. renum. to (8) (am) and am., (8) (b) 2. renum. to (8) (bm) and am., cr. (8) (c) Register June 2019 No. 762, eff. 7-1-19; correction in numbering of (1) (a) made under s. 13.92 (4) (b) 1., and corrections in (1) (a) (intro.), 1., (am), (7) (d) 1. c., 2. made under s. 35.17, Stats., Register June 2019 No. 762; correction in (1) (am) made under s. 13.92 (4) (b) 7., Stats., Register June 2019. NR 422.144(1)(a)(a) This section applies to the owner or operator of a printing facility that operates a letterpress printing press in the county of Kenosha, Milwaukee, Ozaukee, Racine, Sheboygan, Washington, or Waukesha if actual VOC emissions from all letterpress printing presses, including related letterpress cleaning activities at the facility, before consideration of controls, equal or exceed 3 tons on a 12 consecutive month rolling basis. When determining the VOC emissions for applicability under this paragraph, the VOC emissions from the cleaning of electronic components of a letterpress printing press, pre-press and post-press cleaning operations and the use of janitorial supplies used to clean around a letterpress printing press are excluded. The VOC emissions from solvents used in cold cleaners are excluded for applicability purposes.